PbMn(IV)TeO6: A New Noncentrosymmetric Layered Honeycomb Magnetic Oxide

Sun Woo Kim; Zheng Deng; Man Rong Li; Arnab Sen Gupta; Hirofumi Akamatsu; Venkatraman Gopalan; Martha Greenblatt

doi:10.1021/acs.inorgchem.5b02677

PbMn(IV)TeO₆: A New Noncentrosymmetric Layered Honeycomb Magnetic Oxide

Sun Woo Kim, Zheng Deng, Man Rong Li, Arnab Sen Gupta, Hirofumi Akamatsu, Venkatraman Gopalan, Martha Greenblatt

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

PbMnTeO₆, a new noncentrosymmetric layered magnetic oxide was synthesized and characterized. The crystal structure is hexagonal, with space group P62m (No. 189), and consists of edge-sharing (Mn⁴⁺/Te⁶⁺)O₆ trigonal prisms that form honeycomb-like two-dimensional layers with Pb²⁺ ions between the layers. The structural difference between PbMnTeO₆, with disordered/trigonal prisms of Mn⁴⁺/Te⁶⁺, versus the similar chiral SrGeTeO₆ (space group P312), with long-range order of Ge⁴⁺ and Te⁶⁺ in octahedral coordination, is attributed to a difference in the electronic effects of Ge⁴⁺ and Mn⁴⁺. Temperature-dependent second harmonic generation by PbMnTeO₆ confirmed the noncentrosymmetric character between 12 and 873 K. Magnetic measurements indicated antiferromagnetic order at T_N ≈ 20 K and a frustration parameter (|θ|/T_N) of ∼2.16.

Original language	English (US)
Pages (from-to)	1333-1338
Number of pages	6
Journal	Inorganic chemistry
Volume	55
Issue number	3
DOIs	https://doi.org/10.1021/acs.inorgchem.5b02677
State	Published - Feb 1 2016

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/acs.inorgchem.5b02677

Cite this

@article{e74d799e28bb4498a23617c2be193f15,

title = "PbMn(IV)TeO6: A New Noncentrosymmetric Layered Honeycomb Magnetic Oxide",

abstract = "PbMnTeO6, a new noncentrosymmetric layered magnetic oxide was synthesized and characterized. The crystal structure is hexagonal, with space group P62m (No. 189), and consists of edge-sharing (Mn4+/Te6+)O6 trigonal prisms that form honeycomb-like two-dimensional layers with Pb2+ ions between the layers. The structural difference between PbMnTeO6, with disordered/trigonal prisms of Mn4+/Te6+, versus the similar chiral SrGeTeO6 (space group P312), with long-range order of Ge4+ and Te6+ in octahedral coordination, is attributed to a difference in the electronic effects of Ge4+ and Mn4+. Temperature-dependent second harmonic generation by PbMnTeO6 confirmed the noncentrosymmetric character between 12 and 873 K. Magnetic measurements indicated antiferromagnetic order at TN ≈ 20 K and a frustration parameter (|θ|/TN) of ∼2.16.",

author = "Kim, {Sun Woo} and Zheng Deng and Li, {Man Rong} and {Sen Gupta}, Arnab and Hirofumi Akamatsu and Venkatraman Gopalan and Martha Greenblatt",

note = "Funding Information: S.W.K., Z.D., M.R.L., and M.G. gratefully acknowledge support from the ARO-434603 grant (DOD-VV911NF-12-1-0172). A.S.G., H.A., and V.G. gratefully acknowledge support from the National Science Foundation MRSEC Center for Nanoscale Science at Penn State through Grant DMR-1420620. S.W.K. thanks Prof. Mark Croft for fruitful discussions and Graeme Gardner for EDX measurements. Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = feb,

day = "1",

doi = "10.1021/acs.inorgchem.5b02677",

language = "English (US)",

volume = "55",

pages = "1333--1338",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - PbMn(IV)TeO6

T2 - A New Noncentrosymmetric Layered Honeycomb Magnetic Oxide

AU - Kim, Sun Woo

AU - Deng, Zheng

AU - Li, Man Rong

AU - Sen Gupta, Arnab

AU - Akamatsu, Hirofumi

AU - Gopalan, Venkatraman

AU - Greenblatt, Martha

N1 - Funding Information: S.W.K., Z.D., M.R.L., and M.G. gratefully acknowledge support from the ARO-434603 grant (DOD-VV911NF-12-1-0172). A.S.G., H.A., and V.G. gratefully acknowledge support from the National Science Foundation MRSEC Center for Nanoscale Science at Penn State through Grant DMR-1420620. S.W.K. thanks Prof. Mark Croft for fruitful discussions and Graeme Gardner for EDX measurements. Publisher Copyright: © 2016 American Chemical Society.

PY - 2016/2/1

Y1 - 2016/2/1

N2 - PbMnTeO6, a new noncentrosymmetric layered magnetic oxide was synthesized and characterized. The crystal structure is hexagonal, with space group P62m (No. 189), and consists of edge-sharing (Mn4+/Te6+)O6 trigonal prisms that form honeycomb-like two-dimensional layers with Pb2+ ions between the layers. The structural difference between PbMnTeO6, with disordered/trigonal prisms of Mn4+/Te6+, versus the similar chiral SrGeTeO6 (space group P312), with long-range order of Ge4+ and Te6+ in octahedral coordination, is attributed to a difference in the electronic effects of Ge4+ and Mn4+. Temperature-dependent second harmonic generation by PbMnTeO6 confirmed the noncentrosymmetric character between 12 and 873 K. Magnetic measurements indicated antiferromagnetic order at TN ≈ 20 K and a frustration parameter (|θ|/TN) of ∼2.16.

AB - PbMnTeO6, a new noncentrosymmetric layered magnetic oxide was synthesized and characterized. The crystal structure is hexagonal, with space group P62m (No. 189), and consists of edge-sharing (Mn4+/Te6+)O6 trigonal prisms that form honeycomb-like two-dimensional layers with Pb2+ ions between the layers. The structural difference between PbMnTeO6, with disordered/trigonal prisms of Mn4+/Te6+, versus the similar chiral SrGeTeO6 (space group P312), with long-range order of Ge4+ and Te6+ in octahedral coordination, is attributed to a difference in the electronic effects of Ge4+ and Mn4+. Temperature-dependent second harmonic generation by PbMnTeO6 confirmed the noncentrosymmetric character between 12 and 873 K. Magnetic measurements indicated antiferromagnetic order at TN ≈ 20 K and a frustration parameter (|θ|/TN) of ∼2.16.

UR - http://www.scopus.com/inward/record.url?scp=84956641013&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84956641013&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.5b02677

DO - 10.1021/acs.inorgchem.5b02677

M3 - Article

AN - SCOPUS:84956641013

SN - 0020-1669

VL - 55

SP - 1333

EP - 1338

JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 3

ER -

PbMn(IV)TeO₆: A New Noncentrosymmetric Layered Honeycomb Magnetic Oxide

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this