Photochemical activation of α-β epoxyketones. Formation of benzannelated perhydroazulenes by intramolecular trapping of a reactive intermediate

Ken S. Feldman

doi:10.1016/S0040-4039(00)94147-9

Photochemical activation of α-β epoxyketones. Formation of benzannelated perhydroazulenes by intramolecular trapping of a reactive intermediate

Ken S. Feldman

Chemistry

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29 Scopus citations

Abstract

Linear and angular benzannelated perhydroazulenes can be efficiently prepared by intramolecular cycloaddition of unactivated olefins to reactive intermediates generated by irradiation of α-β epoxyketones.

Original language	English (US)
Pages (from-to)	5585-5586
Number of pages	2
Journal	Tetrahedron Letters
Volume	24
Issue number	50
DOIs	https://doi.org/10.1016/S0040-4039(00)94147-9
State	Published - 1983

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)94147-9

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@article{bbd09f31439b4ef2aa81f1a7ab4a863d,

title = "Photochemical activation of α-β epoxyketones. Formation of benzannelated perhydroazulenes by intramolecular trapping of a reactive intermediate",

abstract = "Linear and angular benzannelated perhydroazulenes can be efficiently prepared by intramolecular cycloaddition of unactivated olefins to reactive intermediates generated by irradiation of α-β epoxyketones.",

author = "Feldman, {Ken S.}",

note = "Funding Information: Qknowlegement: I thank Dr. E. E. van Tamelen for his financial support, NSF Grant Che-81-09064 for NMR facilities, and Charles Manly for his assistance in obtaining and interpreting the NOE data.",

year = "1983",

doi = "10.1016/S0040-4039(00)94147-9",

language = "English (US)",

volume = "24",

pages = "5585--5586",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "50",

}

TY - JOUR

T1 - Photochemical activation of α-β epoxyketones. Formation of benzannelated perhydroazulenes by intramolecular trapping of a reactive intermediate

AU - Feldman, Ken S.

N1 - Funding Information: Qknowlegement: I thank Dr. E. E. van Tamelen for his financial support, NSF Grant Che-81-09064 for NMR facilities, and Charles Manly for his assistance in obtaining and interpreting the NOE data.

PY - 1983

Y1 - 1983

N2 - Linear and angular benzannelated perhydroazulenes can be efficiently prepared by intramolecular cycloaddition of unactivated olefins to reactive intermediates generated by irradiation of α-β epoxyketones.

AB - Linear and angular benzannelated perhydroazulenes can be efficiently prepared by intramolecular cycloaddition of unactivated olefins to reactive intermediates generated by irradiation of α-β epoxyketones.

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U2 - 10.1016/S0040-4039(00)94147-9

DO - 10.1016/S0040-4039(00)94147-9

M3 - Article

AN - SCOPUS:0010420223

SN - 0040-4039

VL - 24

SP - 5585

EP - 5586

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 50

ER -

Photochemical activation of α-β epoxyketones. Formation of benzannelated perhydroazulenes by intramolecular trapping of a reactive intermediate

Abstract

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