Photochemical addition of perfluoro-n-butyl iodide to alkynes and olefins

Mohammad H. Habib; Thomas E. Mallouk

doi:10.1016/S0022-1139(00)82238-1

Photochemical addition of perfluoro-n-butyl iodide to alkynes and olefins

Mohammad H. Habib, Thomas E. Mallouk

Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Perfluoro-n-butyl iodide reacts photochemically with alkynes and other unsaturated organic compounds to give the corresponding adducts in quantitative yields. The kinetics of addition were studied by ¹⁹F-NMR, and indicated that the reaction involves a free radical mechanism.

Original language	English (US)
Pages (from-to)	53-60
Number of pages	8
Journal	Journal of Fluorine Chemistry
Volume	53
Issue number	1
DOIs	https://doi.org/10.1016/S0022-1139(00)82238-1
State	Published - Jun 1991

All Science Journal Classification (ASJC) codes

Biochemistry
Environmental Chemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1016/S0022-1139(00)82238-1

Cite this

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title = "Photochemical addition of perfluoro-n-butyl iodide to alkynes and olefins",

abstract = "Perfluoro-n-butyl iodide reacts photochemically with alkynes and other unsaturated organic compounds to give the corresponding adducts in quantitative yields. The kinetics of addition were studied by 19F-NMR, and indicated that the reaction involves a free radical mechanism.",

author = "Habib, {Mohammad H.} and Mallouk, {Thomas E.}",

note = "Funding Information: This work was supported by grants from the Texas Advanced Research Program and the National Science Foundation (PYI Award CHE-8657729). TEM also thanks the Camille and Henry Dreyfus Foundation for support in the form of a Teacher-Scholar Award.",

year = "1991",

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AU - Habib, Mohammad H.

AU - Mallouk, Thomas E.

N1 - Funding Information: This work was supported by grants from the Texas Advanced Research Program and the National Science Foundation (PYI Award CHE-8657729). TEM also thanks the Camille and Henry Dreyfus Foundation for support in the form of a Teacher-Scholar Award.

PY - 1991/6

Y1 - 1991/6

N2 - Perfluoro-n-butyl iodide reacts photochemically with alkynes and other unsaturated organic compounds to give the corresponding adducts in quantitative yields. The kinetics of addition were studied by 19F-NMR, and indicated that the reaction involves a free radical mechanism.

AB - Perfluoro-n-butyl iodide reacts photochemically with alkynes and other unsaturated organic compounds to give the corresponding adducts in quantitative yields. The kinetics of addition were studied by 19F-NMR, and indicated that the reaction involves a free radical mechanism.

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Photochemical addition of perfluoro-n-butyl iodide to alkynes and olefins

Abstract

All Science Journal Classification (ASJC) codes

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