TY - JOUR
T1 - Photochemical selective fluorination of organic molecules using mercury (II) fluoride
AU - Habibi, Mohammed H.
AU - Mallouk, Thomas E.
N1 - Funding Information:
This work was supported by grants from the Texas Advanced Research Program and the National Science Foundation (PYI Award CHE-8657729). TEM also thanks the Camille and Henry Dreyfus Foundation for support in the form of a Teacher-Scholar Award.
PY - 1991/2
Y1 - 1991/2
N2 - Organic compounds, such as triphenylacetic acid, triphenyl ethylene, and triethyl phosphite can be selectively fluorinated in dimethylsulfoxide/ HgF2 solutions under UV-visible illumination. Product yields, determined by 19F-NMR, are essentially quantitative for the compounds studied, and in some cases only a single fluorinated product is formed.
AB - Organic compounds, such as triphenylacetic acid, triphenyl ethylene, and triethyl phosphite can be selectively fluorinated in dimethylsulfoxide/ HgF2 solutions under UV-visible illumination. Product yields, determined by 19F-NMR, are essentially quantitative for the compounds studied, and in some cases only a single fluorinated product is formed.
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U2 - 10.1016/S0022-1139(00)80299-7
DO - 10.1016/S0022-1139(00)80299-7
M3 - Article
AN - SCOPUS:1642368952
SN - 0022-1139
VL - 51
SP - 291
EP - 294
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
IS - 2
ER -