Photochemistry of 2-indolyl aryl ethers: An unexpected rearrangement leading to C-C bond formation

Ken S. Feldman; Daniela Boneva Vidulova

doi:10.3987/com-03-9762

Photochemistry of 2-indolyl aryl ethers: An unexpected rearrangement leading to C-C bond formation

Ken S. Feldman, Daniela Boneva Vidulova

Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Two types of 2-(p-tolyloxy)indole were prepared and their reactivity was studied under photochemical conditions. The expected electrocyclization was not observed. Instead, unprecedented rearrangement products were obtained. The reaction outcome was found to depend on the viscosity of the media.

Original language	English (US)
Pages (from-to)	1615-1623
Number of pages	9
Journal	Heterocycles
Volume	60
Issue number	7
DOIs	https://doi.org/10.3987/com-03-9762
State	Published - Jul 1 2003

All Science Journal Classification (ASJC) codes

Analytical Chemistry
Pharmacology
Organic Chemistry

Access to Document

10.3987/com-03-9762

Cite this

@article{d9b23dc8596543d5a4a26118a733c73e,

title = "Photochemistry of 2-indolyl aryl ethers: An unexpected rearrangement leading to C-C bond formation",

abstract = "Two types of 2-(p-tolyloxy)indole were prepared and their reactivity was studied under photochemical conditions. The expected electrocyclization was not observed. Instead, unprecedented rearrangement products were obtained. The reaction outcome was found to depend on the viscosity of the media.",

author = "Feldman, {Ken S.} and Vidulova, {Daniela Boneva}",

year = "2003",

month = jul,

day = "1",

doi = "10.3987/com-03-9762",

language = "English (US)",

volume = "60",

pages = "1615--1623",

journal = "Heterocycles",

issn = "0385-5414",

publisher = "Japan Institute of Heterocyclic Chemistry",

number = "7",

}

TY - JOUR

T1 - Photochemistry of 2-indolyl aryl ethers

T2 - An unexpected rearrangement leading to C-C bond formation

AU - Feldman, Ken S.

AU - Vidulova, Daniela Boneva

PY - 2003/7/1

Y1 - 2003/7/1

N2 - Two types of 2-(p-tolyloxy)indole were prepared and their reactivity was studied under photochemical conditions. The expected electrocyclization was not observed. Instead, unprecedented rearrangement products were obtained. The reaction outcome was found to depend on the viscosity of the media.

AB - Two types of 2-(p-tolyloxy)indole were prepared and their reactivity was studied under photochemical conditions. The expected electrocyclization was not observed. Instead, unprecedented rearrangement products were obtained. The reaction outcome was found to depend on the viscosity of the media.

UR - http://www.scopus.com/inward/record.url?scp=0037926635&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037926635&partnerID=8YFLogxK

U2 - 10.3987/com-03-9762

DO - 10.3987/com-03-9762

M3 - Article

AN - SCOPUS:0037926635

SN - 0385-5414

VL - 60

SP - 1615

EP - 1623

JO - Heterocycles

JF - Heterocycles

IS - 7

ER -

Photochemistry of 2-indolyl aryl ethers: An unexpected rearrangement leading to C-C bond formation

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this