TY - JOUR
T1 - Photoluminescence Enhancement of Titanate Nanotubes by Insertion of Rare Earth Ions in Their Interlayer Spaces
AU - Marques, Thalles M.F.
AU - Luz-Lima, Cleanio
AU - Sacilloti, Marco
AU - Fujisawa, Kazunori
AU - Perea-Lopez, Nestor
AU - Terrones, Mauricio
AU - Silva, Eder Nascimento
AU - Ferreira, Odair Pastor
AU - Viana, Bartolomeu Cruz
N1 - Publisher Copyright:
© 2017 Thalles M. F. Marques et al.
PY - 2017
Y1 - 2017
N2 - The optical properties of titanate nanotubes (TiNts) intercalated with rare earths (RE) ions were intensively investigated in this study. To prepare the nanomaterials, sodium titanate nanotubes (Na-TiNts) were submitted to ion exchange reactions with different rare earth elements (RE: Pr3+, Er3+, Nd3+, and Yb3+). To the best of our knowledge, it is the first time that these RE-TiNts were synthesized. All samples were characterized by Raman spectroscopy, X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and energy dispersive X-ray spectroscopy (EDS). Furthermore, the optical properties were examined using photoluminescence spectroscopy (PL) and UV-Vis-NIR absorption spectroscopy. The PL intensity (visible range) of the RE-TiNt samples showed a strong dependence when the temperature was decreased down to 20 K. This PL enhancement probably was promoted by electronic modifications in titanate layer band gap and/or interface charge transfers due to RE ions intercalation.
AB - The optical properties of titanate nanotubes (TiNts) intercalated with rare earths (RE) ions were intensively investigated in this study. To prepare the nanomaterials, sodium titanate nanotubes (Na-TiNts) were submitted to ion exchange reactions with different rare earth elements (RE: Pr3+, Er3+, Nd3+, and Yb3+). To the best of our knowledge, it is the first time that these RE-TiNts were synthesized. All samples were characterized by Raman spectroscopy, X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and energy dispersive X-ray spectroscopy (EDS). Furthermore, the optical properties were examined using photoluminescence spectroscopy (PL) and UV-Vis-NIR absorption spectroscopy. The PL intensity (visible range) of the RE-TiNt samples showed a strong dependence when the temperature was decreased down to 20 K. This PL enhancement probably was promoted by electronic modifications in titanate layer band gap and/or interface charge transfers due to RE ions intercalation.
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U2 - 10.1155/2017/3809807
DO - 10.1155/2017/3809807
M3 - Article
AN - SCOPUS:85012188426
SN - 1687-4110
VL - 2017
JO - Journal of Nanomaterials
JF - Journal of Nanomaterials
M1 - 3809807
ER -