Piezoelectric properties of Sb-, Li-, and Mn-substituted Pb(Zr xTi1-x)O3-Pb(Zn1/3Nb 2/3)O3-Pb(Ni1/3Nb2/3)O3 ceramics for high-power applications

Seung Ho Park; Seyit Ural; Cheol Woo Ahn; Sahn Nahm; Kenji Uchino

doi:10.1143/JJAP.45.2667

Piezoelectric properties of Sb-, Li-, and Mn-substituted Pb(Zr _xTi_1-x)O₃-Pb(Zn_1/3Nb _2/3)O₃-Pb(Ni_1/3Nb_2/3)O₃ ceramics for high-power applications

Seung Ho Park
, Seyit Ural
, Cheol Woo Ahn
, Sahn Nahm
, Kenji Uchino

Materials Research Institute (MRI)

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

We developed piezoelectric ceramics suitable for high-power piezoelectric transformer applications. Sb, Li, and Mn were substituted in the 0.8Pb(Zr _0.5Ti_0.5)O₃-0.16Pb(Zn_1/3Nb _2/3)O₃-0.04Pb(Ni_2/3Nb_2/3)O ₃ ceramics. All these substituents changed the structure of a tetragonal composition to cubical phase. The Sb and Li substitutions resulted in increases in k_p and d₃₃, whereas Mn substitution increased Q_m. The composition 0.8Pb(Zr_xTi _1-x)-0.2Pb[(1 - c){(1 - b)(Zn_0.8Ni_0.2) _1/3(Nb_1-aSb_a)_2/3-b(Li _1/4(Nb_1-aSb_a)_3/4)}-c(Mn _1/3(Nb_1-aSb_a)_2/3)]O₃ (a = 0.1, b = 0.3, c = 0.3, and x = 0.5) showed k_p = 0.56, Q_m = 1951 (planar mode), d₃₃ = 239 pC/N, ε₃ ^T/ε₀ = 739 and a maximum vibration velocity = 0.6 m/ s in the 31 mode. By adjusting Zr/ Ti ratio, the structure of the ceramics reverted to the morphotropic phase boundary and showed k_p = 0.57, Q_m = 1502 (planar mode), d₃₃ = 330pC/N, ε ₃^T/ε₀ = 1653 and a maximum 31 mode vibration velocity = 0.58 m/s when Zr/Ti = 0.48/0.52.

Original language	English (US)
Pages (from-to)	2667-2673
Number of pages	7
Journal	Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
Volume	45
Issue number	4 A
DOIs	https://doi.org/10.1143/JJAP.45.2667
State	Published - Apr 7 2006

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General Engineering
General Physics and Astronomy

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10.1143/JJAP.45.2667

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@article{aa333129c0ca484fa0fd20a642786e3c,

title = "Piezoelectric properties of Sb-, Li-, and Mn-substituted Pb(Zr xTi1-x)O3-Pb(Zn1/3Nb 2/3)O3-Pb(Ni1/3Nb2/3)O3 ceramics for high-power applications",

abstract = "We developed piezoelectric ceramics suitable for high-power piezoelectric transformer applications. Sb, Li, and Mn were substituted in the 0.8Pb(Zr 0.5Ti0.5)O3-0.16Pb(Zn1/3Nb 2/3)O3-0.04Pb(Ni2/3Nb2/3)O 3 ceramics. All these substituents changed the structure of a tetragonal composition to cubical phase. The Sb and Li substitutions resulted in increases in kp and d33, whereas Mn substitution increased Qm. The composition 0.8Pb(ZrxTi 1-x)-0.2Pb[(1 - c)\{(1 - b)(Zn0.8Ni0.2) 1/3(Nb1-aSba)2/3-b(Li 1/4(Nb1-aSba)3/4)\}-c(Mn 1/3(Nb1-aSba)2/3)]O3 (a = 0.1, b = 0.3, c = 0.3, and x = 0.5) showed kp = 0.56, Qm = 1951 (planar mode), d33 = 239 pC/N, ε3 T/ε0 = 739 and a maximum vibration velocity = 0.6 m/ s in the 31 mode. By adjusting Zr/ Ti ratio, the structure of the ceramics reverted to the morphotropic phase boundary and showed kp = 0.57, Qm = 1502 (planar mode), d33 = 330pC/N, ε 3T/ε0 = 1653 and a maximum 31 mode vibration velocity = 0.58 m/s when Zr/Ti = 0.48/0.52.",

author = "Park, \{Seung Ho\} and Seyit Ural and Ahn, \{Cheol Woo\} and Sahn Nahm and Kenji Uchino",

year = "2006",

month = apr,

day = "7",

doi = "10.1143/JJAP.45.2667",

language = "English (US)",

volume = "45",

pages = "2667--2673",

journal = "Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers",

issn = "0021-4922",

publisher = "Institute of Physics",

number = "4 A",

}

Piezoelectric properties of Sb-, Li-, and Mn-substituted Pb(Zr _xTi_1-x)O₃-Pb(Zn_1/3Nb _2/3)O₃-Pb(Ni_1/3Nb_2/3)O₃ ceramics for high-power applications. / Park, Seung Ho; Ural, Seyit; Ahn, Cheol Woo et al.
In: Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, Vol. 45, No. 4 A, 07.04.2006, p. 2667-2673.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Piezoelectric properties of Sb-, Li-, and Mn-substituted Pb(Zr xTi1-x)O3-Pb(Zn1/3Nb 2/3)O3-Pb(Ni1/3Nb2/3)O3 ceramics for high-power applications

AU - Park, Seung Ho

AU - Ural, Seyit

AU - Ahn, Cheol Woo

AU - Nahm, Sahn

AU - Uchino, Kenji

PY - 2006/4/7

Y1 - 2006/4/7

N2 - We developed piezoelectric ceramics suitable for high-power piezoelectric transformer applications. Sb, Li, and Mn were substituted in the 0.8Pb(Zr 0.5Ti0.5)O3-0.16Pb(Zn1/3Nb 2/3)O3-0.04Pb(Ni2/3Nb2/3)O 3 ceramics. All these substituents changed the structure of a tetragonal composition to cubical phase. The Sb and Li substitutions resulted in increases in kp and d33, whereas Mn substitution increased Qm. The composition 0.8Pb(ZrxTi 1-x)-0.2Pb[(1 - c){(1 - b)(Zn0.8Ni0.2) 1/3(Nb1-aSba)2/3-b(Li 1/4(Nb1-aSba)3/4)}-c(Mn 1/3(Nb1-aSba)2/3)]O3 (a = 0.1, b = 0.3, c = 0.3, and x = 0.5) showed kp = 0.56, Qm = 1951 (planar mode), d33 = 239 pC/N, ε3 T/ε0 = 739 and a maximum vibration velocity = 0.6 m/ s in the 31 mode. By adjusting Zr/ Ti ratio, the structure of the ceramics reverted to the morphotropic phase boundary and showed kp = 0.57, Qm = 1502 (planar mode), d33 = 330pC/N, ε 3T/ε0 = 1653 and a maximum 31 mode vibration velocity = 0.58 m/s when Zr/Ti = 0.48/0.52.

AB - We developed piezoelectric ceramics suitable for high-power piezoelectric transformer applications. Sb, Li, and Mn were substituted in the 0.8Pb(Zr 0.5Ti0.5)O3-0.16Pb(Zn1/3Nb 2/3)O3-0.04Pb(Ni2/3Nb2/3)O 3 ceramics. All these substituents changed the structure of a tetragonal composition to cubical phase. The Sb and Li substitutions resulted in increases in kp and d33, whereas Mn substitution increased Qm. The composition 0.8Pb(ZrxTi 1-x)-0.2Pb[(1 - c){(1 - b)(Zn0.8Ni0.2) 1/3(Nb1-aSba)2/3-b(Li 1/4(Nb1-aSba)3/4)}-c(Mn 1/3(Nb1-aSba)2/3)]O3 (a = 0.1, b = 0.3, c = 0.3, and x = 0.5) showed kp = 0.56, Qm = 1951 (planar mode), d33 = 239 pC/N, ε3 T/ε0 = 739 and a maximum vibration velocity = 0.6 m/ s in the 31 mode. By adjusting Zr/ Ti ratio, the structure of the ceramics reverted to the morphotropic phase boundary and showed kp = 0.57, Qm = 1502 (planar mode), d33 = 330pC/N, ε 3T/ε0 = 1653 and a maximum 31 mode vibration velocity = 0.58 m/s when Zr/Ti = 0.48/0.52.

UR - https://www.scopus.com/pages/publications/33645694639

UR - https://www.scopus.com/pages/publications/33645694639#tab=citedBy

U2 - 10.1143/JJAP.45.2667

DO - 10.1143/JJAP.45.2667

M3 - Article

AN - SCOPUS:33645694639

SN - 0021-4922

VL - 45

SP - 2667

EP - 2673

JO - Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers

JF - Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers

IS - 4 A

ER -

Piezoelectric properties of Sb-, Li-, and Mn-substituted Pb(Zr _xTi_1-x)O₃-Pb(Zn_1/3Nb _2/3)O₃-Pb(Ni_1/3Nb_2/3)O₃ ceramics for high-power applications

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