@inproceedings{69b4c271cbad42f18cd07fa6c760cddf,
title = "POLYMER ELECTROLYTES BASED ON POLYPHOSPHAZENE BACKBONES.",
abstract = "Polar polymers containing alkali metal salts, function as solid electrolytes. The conductivity of these materials is greatest when the polymer has a high degree of segmental motion, as indicated by a low value of T//g. Comblike polymers with short-chain polyether side chains on a polyphosphazene backbone have low values of T//g and these form polymer salt complexes with good conductivity. The conductivity is however sensitive to composition of these polymer salt complexes. For example, the conductivity goes through a maximum as a function of increasing salt concentration and the conductivity is strongly influence by the structure of the side chains. Recent **1**3C NMR spectroscopic give some insight into the mode of coordination of the alkali metal to the side chains and the role of side chain structure in determining conductivity.",
author = "Shriver, {D. F.} and Tonge, {J. S.} and A. Barriola and Blonsky, {P. M.} and Allcock, {H. R.} and S. Kwon and P. Austin",
year = "1987",
month = jan,
day = "1",
language = "English (US)",
isbn = "0841210519",
series = "Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material",
publisher = "ACS",
booktitle = "Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material",
}