Poly(organophosphazenes): Synthesis, unique properties, and applications

Harry R. Allcock

doi:10.1002/masy.19860060112

Poly(organophosphazenes): Synthesis, unique properties, and applications

Harry R. Allcock

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Abstract

Poly(organophosphazenes) are the first inorganic backbone polymers to be developed on a broad scale since the discovery of the silicones in the 1940's. Polyphosphazenes are synthesized by ring‐opening polymerization of cyclic halogenophosphazenes, followed by nucleophilic replacement of the halogen atoms in the polymer by organic units. Factors that affect the ring‐opening polymerization are discussed, together with the properties and uses of the new polymers.

Original language	English (US)
Pages (from-to)	101-108
Number of pages	8
Journal	Makromolekulare Chemie. Macromolecular Symposia
Volume	6
Issue number	1
DOIs	https://doi.org/10.1002/masy.19860060112
State	Published - Dec 1986

All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/masy.19860060112

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abstract = "Poly(organophosphazenes) are the first inorganic backbone polymers to be developed on a broad scale since the discovery of the silicones in the 1940's. Polyphosphazenes are synthesized by ring‐opening polymerization of cyclic halogenophosphazenes, followed by nucleophilic replacement of the halogen atoms in the polymer by organic units. Factors that affect the ring‐opening polymerization are discussed, together with the properties and uses of the new polymers.",

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AB - Poly(organophosphazenes) are the first inorganic backbone polymers to be developed on a broad scale since the discovery of the silicones in the 1940's. Polyphosphazenes are synthesized by ring‐opening polymerization of cyclic halogenophosphazenes, followed by nucleophilic replacement of the halogen atoms in the polymer by organic units. Factors that affect the ring‐opening polymerization are discussed, together with the properties and uses of the new polymers.

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Poly(organophosphazenes): Synthesis, unique properties, and applications

Abstract

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