Preparation and X-ray structures of 2-[(aryl)iodonio]benzenesulfonates: novel diaryliodonium betaines

Michael W. Justik; John D. Protasiewicz; James B. Updegraff

doi:10.1016/j.tetlet.2009.08.067

Preparation and X-ray structures of 2-[(aryl)iodonio]benzenesulfonates: novel diaryliodonium betaines

Michael W. Justik
, John D. Protasiewicz
, James B. Updegraff

School of Science (Behrend)

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Herein we present a concise preparation and characterization of 2-[(aryl)iodonio]benzenesulfonates. Determination of the X-ray crystal structure reveals a distorted trigonal bipyramidal molecular geometry about iodine and a pseudo-square geometry within the unit cell. Initial experiments point to the promising application of these compounds for unique 2-sulfonyloxyarenes.

Original language	English (US)
Pages (from-to)	6072-6075
Number of pages	4
Journal	Tetrahedron Letters
Volume	50
Issue number	44
DOIs	https://doi.org/10.1016/j.tetlet.2009.08.067
State	Published - Nov 4 2009

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2009.08.067

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title = "Preparation and X-ray structures of 2-[(aryl)iodonio]benzenesulfonates: novel diaryliodonium betaines",

abstract = "Herein we present a concise preparation and characterization of 2-[(aryl)iodonio]benzenesulfonates. Determination of the X-ray crystal structure reveals a distorted trigonal bipyramidal molecular geometry about iodine and a pseudo-square geometry within the unit cell. Initial experiments point to the promising application of these compounds for unique 2-sulfonyloxyarenes.",

author = "Justik, \{Michael W.\} and Protasiewicz, \{John D.\} and Updegraff, \{James B.\}",

note = "Funding Information: M.W.J. wishes to thank the School of Science at Penn State Eriefor start-up funds to conduct this work as well as the Thomas Lord Charitable Trust, and The Orris C. Hirtzel and Beatrice Dewey Hirtzel Memorial Foundation for the 400 MHz NMR facility. J.D.P. would like to thank NSF for the support in the form of funds to purchase the single crystal X-ray diffractometer used in this study (CHE 0541766). Copyright: Copyright 2009 Elsevier B.V., All rights reserved.",

year = "2009",

month = nov,

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doi = "10.1016/j.tetlet.2009.08.067",

language = "English (US)",

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T1 - Preparation and X-ray structures of 2-[(aryl)iodonio]benzenesulfonates

T2 - novel diaryliodonium betaines

AU - Justik, Michael W.

AU - Protasiewicz, John D.

AU - Updegraff, James B.

N1 - Funding Information: M.W.J. wishes to thank the School of Science at Penn State Eriefor start-up funds to conduct this work as well as the Thomas Lord Charitable Trust, and The Orris C. Hirtzel and Beatrice Dewey Hirtzel Memorial Foundation for the 400 MHz NMR facility. J.D.P. would like to thank NSF for the support in the form of funds to purchase the single crystal X-ray diffractometer used in this study (CHE 0541766). Copyright: Copyright 2009 Elsevier B.V., All rights reserved.

PY - 2009/11/4

Y1 - 2009/11/4

N2 - Herein we present a concise preparation and characterization of 2-[(aryl)iodonio]benzenesulfonates. Determination of the X-ray crystal structure reveals a distorted trigonal bipyramidal molecular geometry about iodine and a pseudo-square geometry within the unit cell. Initial experiments point to the promising application of these compounds for unique 2-sulfonyloxyarenes.

AB - Herein we present a concise preparation and characterization of 2-[(aryl)iodonio]benzenesulfonates. Determination of the X-ray crystal structure reveals a distorted trigonal bipyramidal molecular geometry about iodine and a pseudo-square geometry within the unit cell. Initial experiments point to the promising application of these compounds for unique 2-sulfonyloxyarenes.

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DO - 10.1016/j.tetlet.2009.08.067

M3 - Article

AN - SCOPUS:70149108071

SN - 0040-4039

VL - 50

SP - 6072

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 44

ER -

Preparation and X-ray structures of 2-[(aryl)iodonio]benzenesulfonates: novel diaryliodonium betaines

Abstract

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