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Preparation of C60 bonded poly(N-vinylcarbazole) with C60Cln/CuCl/Bpy catalyst system

  • Richard E. Buller
  • , Mark S. Shahin
  • , Jo Ann Horowitz
  • , Ingo B. Runnebaum
  • , Vikas Mahavni
  • , Stan Petrauskas
  • , Rolf Kreienberg
  • , Beth Karlan
  • , Dennis Slamon
  • , Mark Pegram

Research output: Contribution to journalArticlepeer-review

Abstract

C60 bonded poly(N-vinylcarbazole) has been synthesized by C60Cln (the average value of n is 20)/CuCl/2,2'-bipyridine (Bpy) catalyst system and its structure was analyzed by UV-Vis and proton NMR. The polymerization mechanism was proposed proceeding via an atom transfer radical polymerization (ATRP). The photoconducting properties of C60 bonded poly(N-vinylcarbazole) was better than poly(N-vinylcarbazole) initiated by AIBN.

Original languageEnglish (US)
Pages (from-to)135-141
Number of pages7
JournalPolymer Bulletin
Volume48
Issue number2
DOIs
StatePublished - 2002

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • Condensed Matter Physics
  • Polymers and Plastics
  • Materials Chemistry

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