Preparation of modified SiO2 colloidal spheres with succinic acid and the assembly of colloidal crystals

Jun Fang; Xiu Feng Wang; Lie Song Wang; Bing Cheng; Yuan Ting Wu; Wan Lin Zhu

doi:10.1007/s11434-007-0091-6

Preparation of modified SiO₂ colloidal spheres with succinic acid and the assembly of colloidal crystals

Jun Fang, Xiu Feng Wang, Lie Song Wang, Bing Cheng, Yuan Ting Wu, Wan Lin Zhu

Materials Characterization Lab

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

SiO₂ colloidal spheres were synthesized by Stöber method. In order to enhance surface charge of the SiO₂ spheres, they were modified with succinic acid. Scanning electron microscope (SEM) shows that the average size of modified SiO₂ spheres is 473 nm, and its distribution standard deviation is less than 5%; Fourier-transform infrared spectra (FT-IR) and X-ray photoelectron spectrometer (XPS) results indicate that one end of succinic acid is chemically bonded to the SiO₂ spheres through esterification; Zeta potential of the modified SiO₂ spheres in water solution is improved from -53.72 to -67.46 mV, and surface charge density of the modified SiO₂ spheres is enhanced from 0.19 to 0.94 μC/cm ². SiO₂ colloidal crystal was fabricated from aqueous colloidal solution by the vertical deposition method at 40°C and 60% relative humidity. SEM images show that the sample of SiO₂ colloidal crystal is face-centered cubic (fcc) structure with its (111) planes parallel to the substrate. Transmission measurement shows the existence of photonic band gap at 1047 nm.

Original language	English (US)
Pages (from-to)	461-466
Number of pages	6
Journal	Chinese Science Bulletin
Volume	52
Issue number	4
DOIs	https://doi.org/10.1007/s11434-007-0091-6
State	Published - Feb 2007

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@article{26d57fbafa8f400e9dc44f2fc58109d9,

title = "Preparation of modified SiO2 colloidal spheres with succinic acid and the assembly of colloidal crystals",

abstract = "SiO2 colloidal spheres were synthesized by St{\"o}ber method. In order to enhance surface charge of the SiO2 spheres, they were modified with succinic acid. Scanning electron microscope (SEM) shows that the average size of modified SiO2 spheres is 473 nm, and its distribution standard deviation is less than 5%; Fourier-transform infrared spectra (FT-IR) and X-ray photoelectron spectrometer (XPS) results indicate that one end of succinic acid is chemically bonded to the SiO2 spheres through esterification; Zeta potential of the modified SiO2 spheres in water solution is improved from -53.72 to -67.46 mV, and surface charge density of the modified SiO2 spheres is enhanced from 0.19 to 0.94 μC/cm 2. SiO2 colloidal crystal was fabricated from aqueous colloidal solution by the vertical deposition method at 40°C and 60% relative humidity. SEM images show that the sample of SiO2 colloidal crystal is face-centered cubic (fcc) structure with its (111) planes parallel to the substrate. Transmission measurement shows the existence of photonic band gap at 1047 nm.",

author = "Jun Fang and Wang, {Xiu Feng} and Wang, {Lie Song} and Bing Cheng and Wu, {Yuan Ting} and Zhu, {Wan Lin}",

note = "Funding Information: Received July 13, 2006; accepted November 11, 2006 doi: 10.1007/s11434-007-0091-6 †Corresponding author (email: [email protected]) Supported by the National Natural Science Foundation 50372038)",

year = "2007",

month = feb,

doi = "10.1007/s11434-007-0091-6",

language = "English (US)",

volume = "52",

pages = "461--466",

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TY - JOUR

T1 - Preparation of modified SiO2 colloidal spheres with succinic acid and the assembly of colloidal crystals

AU - Fang, Jun

AU - Wang, Xiu Feng

AU - Wang, Lie Song

AU - Cheng, Bing

AU - Wu, Yuan Ting

AU - Zhu, Wan Lin

N1 - Funding Information: Received July 13, 2006; accepted November 11, 2006 doi: 10.1007/s11434-007-0091-6 †Corresponding author (email: [email protected]) Supported by the National Natural Science Foundation 50372038)

PY - 2007/2

Y1 - 2007/2

N2 - SiO2 colloidal spheres were synthesized by Stöber method. In order to enhance surface charge of the SiO2 spheres, they were modified with succinic acid. Scanning electron microscope (SEM) shows that the average size of modified SiO2 spheres is 473 nm, and its distribution standard deviation is less than 5%; Fourier-transform infrared spectra (FT-IR) and X-ray photoelectron spectrometer (XPS) results indicate that one end of succinic acid is chemically bonded to the SiO2 spheres through esterification; Zeta potential of the modified SiO2 spheres in water solution is improved from -53.72 to -67.46 mV, and surface charge density of the modified SiO2 spheres is enhanced from 0.19 to 0.94 μC/cm 2. SiO2 colloidal crystal was fabricated from aqueous colloidal solution by the vertical deposition method at 40°C and 60% relative humidity. SEM images show that the sample of SiO2 colloidal crystal is face-centered cubic (fcc) structure with its (111) planes parallel to the substrate. Transmission measurement shows the existence of photonic band gap at 1047 nm.

AB - SiO2 colloidal spheres were synthesized by Stöber method. In order to enhance surface charge of the SiO2 spheres, they were modified with succinic acid. Scanning electron microscope (SEM) shows that the average size of modified SiO2 spheres is 473 nm, and its distribution standard deviation is less than 5%; Fourier-transform infrared spectra (FT-IR) and X-ray photoelectron spectrometer (XPS) results indicate that one end of succinic acid is chemically bonded to the SiO2 spheres through esterification; Zeta potential of the modified SiO2 spheres in water solution is improved from -53.72 to -67.46 mV, and surface charge density of the modified SiO2 spheres is enhanced from 0.19 to 0.94 μC/cm 2. SiO2 colloidal crystal was fabricated from aqueous colloidal solution by the vertical deposition method at 40°C and 60% relative humidity. SEM images show that the sample of SiO2 colloidal crystal is face-centered cubic (fcc) structure with its (111) planes parallel to the substrate. Transmission measurement shows the existence of photonic band gap at 1047 nm.

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Preparation of modified SiO₂ colloidal spheres with succinic acid and the assembly of colloidal crystals

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