Pure- and mixed-gas sorption measurements on zeolitic adsorbents via gas-phase nuclear magnetic resonance

Frank Rittig; David J. Aurentz; Charles G. Coe; Ronald J. Kitzhoffer; John M. Zielinski

doi:10.1021/ie020133o

Pure- and mixed-gas sorption measurements on zeolitic adsorbents via gas-phase nuclear magnetic resonance

Frank Rittig
, David J. Aurentz
, Charles G. Coe
, Ronald J. Kitzhoffer
, John M. Zielinski

Division of Science (Berks)

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Gas-phase NMR spectroscopy has been applied successfully in measuring pure- and mixed-gas equilibria on a 5A adsorbent for carbon monoxide, methane, and nitrogen. The reliability of the technique is established by comparing data collected here to pure-gas isotherms measured at 23 °C by standard volumetric expansion techniques in the pressure range of 0.5-5 atm. Mixed-gas equilibria data for binary gas mixtures as well as the ternary gas mixture are compared with predictions based on heterogeneous ideal solution adsorption theory analysis.

Original language	English (US)
Pages (from-to)	4430-4434
Number of pages	5
Journal	Industrial and Engineering Chemistry Research
Volume	41
Issue number	17
DOIs	https://doi.org/10.1021/ie020133o
State	Published - Aug 21 2002

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

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10.1021/ie020133o

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abstract = "Gas-phase NMR spectroscopy has been applied successfully in measuring pure- and mixed-gas equilibria on a 5A adsorbent for carbon monoxide, methane, and nitrogen. The reliability of the technique is established by comparing data collected here to pure-gas isotherms measured at 23 °C by standard volumetric expansion techniques in the pressure range of 0.5-5 atm. Mixed-gas equilibria data for binary gas mixtures as well as the ternary gas mixture are compared with predictions based on heterogeneous ideal solution adsorption theory analysis.",

author = "Frank Rittig and Aurentz, \{David J.\} and Coe, \{Charles G.\} and Kitzhoffer, \{Ronald J.\} and Zielinski, \{John M.\}",

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AU - Rittig, Frank

AU - Aurentz, David J.

AU - Coe, Charles G.

AU - Kitzhoffer, Ronald J.

AU - Zielinski, John M.

PY - 2002/8/21

Y1 - 2002/8/21

N2 - Gas-phase NMR spectroscopy has been applied successfully in measuring pure- and mixed-gas equilibria on a 5A adsorbent for carbon monoxide, methane, and nitrogen. The reliability of the technique is established by comparing data collected here to pure-gas isotherms measured at 23 °C by standard volumetric expansion techniques in the pressure range of 0.5-5 atm. Mixed-gas equilibria data for binary gas mixtures as well as the ternary gas mixture are compared with predictions based on heterogeneous ideal solution adsorption theory analysis.

AB - Gas-phase NMR spectroscopy has been applied successfully in measuring pure- and mixed-gas equilibria on a 5A adsorbent for carbon monoxide, methane, and nitrogen. The reliability of the technique is established by comparing data collected here to pure-gas isotherms measured at 23 °C by standard volumetric expansion techniques in the pressure range of 0.5-5 atm. Mixed-gas equilibria data for binary gas mixtures as well as the ternary gas mixture are compared with predictions based on heterogeneous ideal solution adsorption theory analysis.

UR - https://www.scopus.com/pages/publications/0037151545

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U2 - 10.1021/ie020133o

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JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 17

ER -

Pure- and mixed-gas sorption measurements on zeolitic adsorbents via gas-phase nuclear magnetic resonance

Abstract

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