Quadrupole contribution to the physisorption interaction

Xue Pei Jiang; Flavio Toigo; Milton W. Cole

doi:10.1016/0009-2614(83)87362-X

Quadrupole contribution to the physisorption interaction

Xue Pei Jiang
, Flavio Toigo
, Milton W. Cole

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

We compute the quadrupole dispersion contribution to the adsorption potential of non-polar atoms. Two methods are used. One assumes a perfect induced image. The other applies perturbation theory to treat surface plasmon fluctuations interacting with quadrupolar fluctuations. The resulting interaction (-C₅z^-5 can be important near the adatom′s equilibrium position.

Original language	English (US)
Pages (from-to)	159-162
Number of pages	4
Journal	Chemical Physics Letters
Volume	101
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(83)87362-X
State	Published - Oct 14 1983

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1016/0009-2614(83)87362-X

Cite this

@article{10f921ac870e4f13aa2816346d95fbee,

title = "Quadrupole contribution to the physisorption interaction",

abstract = "We compute the quadrupole dispersion contribution to the adsorption potential of non-polar atoms. Two methods are used. One assumes a perfect induced image. The other applies perturbation theory to treat surface plasmon fluctuations interacting with quadrupolar fluctuations. The resulting interaction (-C5z-5 can be important near the adatom′s equilibrium position.",

author = "Jiang, \{Xue Pei\} and Flavio Toigo and Cole, \{Milton W.\}",

note = "Funding Information: * Research supported in part by NSF grant DhIR-8113262, DOE Contract DE-Ah103-76SF00767 and theCNR through the Italy-US Cooperative Program. + Present address.",

year = "1983",

month = oct,

day = "14",

doi = "10.1016/0009-2614(83)87362-X",

language = "English (US)",

volume = "101",

pages = "159--162",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Quadrupole contribution to the physisorption interaction

AU - Jiang, Xue Pei

AU - Toigo, Flavio

AU - Cole, Milton W.

N1 - Funding Information: * Research supported in part by NSF grant DhIR-8113262, DOE Contract DE-Ah103-76SF00767 and theCNR through the Italy-US Cooperative Program. + Present address.

PY - 1983/10/14

Y1 - 1983/10/14

N2 - We compute the quadrupole dispersion contribution to the adsorption potential of non-polar atoms. Two methods are used. One assumes a perfect induced image. The other applies perturbation theory to treat surface plasmon fluctuations interacting with quadrupolar fluctuations. The resulting interaction (-C5z-5 can be important near the adatom′s equilibrium position.

AB - We compute the quadrupole dispersion contribution to the adsorption potential of non-polar atoms. Two methods are used. One assumes a perfect induced image. The other applies perturbation theory to treat surface plasmon fluctuations interacting with quadrupolar fluctuations. The resulting interaction (-C5z-5 can be important near the adatom′s equilibrium position.

UR - https://www.scopus.com/pages/publications/33646621976

UR - https://www.scopus.com/pages/publications/33646621976#tab=citedBy

U2 - 10.1016/0009-2614(83)87362-X

DO - 10.1016/0009-2614(83)87362-X

M3 - Article

AN - SCOPUS:33646621976

SN - 0009-2614

VL - 101

SP - 159

EP - 162

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

Quadrupole contribution to the physisorption interaction

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this