Radiation crosslinking of poly[bis-2-(2-methoxyethoxy)ethoxy]phosphazene: effect on solid state ionic conductivity

Jordan L. Bennett; Alexa A. Dembek; Harry R. Allcock; Bruce J. Heyen; Duward F. Shriver

Radiation crosslinking of poly[bis-2-(2-methoxyethoxy)ethoxy]phosphazene: effect on solid state ionic conductivity

Jordan L. Bennett
, Alexa A. Dembek
, Harry R. Allcock
, Bruce J. Heyen
, Duward F. Shriver

Research output: Contribution to journal › Conference article › peer-review

Abstract

The polyphosphazene, poly[bis(2-2-methoxyethoxy) ethoxy]phosphazene (I), shows excellent promise as a solid electrolyte host when LiCF₃SO₃ is used as the charge carrier. The ionic conductivity of the gamma irradiated crosslinked polymer/salt complexes was investigated through two complementary sets of polymer-electrolyte combinations. In one (series A) the salt was added to the polymer before irradiation, while in the second (series B) the salt was added to a solvent-swelled polymer after irradiation. These experiments were carried out to eliminate the possibility that the presence of LiCF₃SO₃ during irradiation would affect the ionic conductivity of the final product. Series A and B each consisted of six thin films of I with 0.25 equivalent of LiCF₃SO₃ per polymer repeat unit.

Original language	English (US)
Pages (from-to)	437-438
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	30
Issue number	1
State	Published - Apr 1989
Event	Papers Presented at the Dallas, Texas Meeting - Dallas, TX, USA Duration: Apr 9 1989 → Apr 14 1989

All Science Journal Classification (ASJC) codes

Polymers and Plastics

Cite this

@article{64966fd5c36d41369dbde75f0b9203de,

title = "Radiation crosslinking of poly[bis-2-(2-methoxyethoxy)ethoxy]phosphazene: effect on solid state ionic conductivity",

abstract = "The polyphosphazene, poly[bis(2-2-methoxyethoxy) ethoxy]phosphazene (I), shows excellent promise as a solid electrolyte host when LiCF3SO3 is used as the charge carrier. The ionic conductivity of the gamma irradiated crosslinked polymer/salt complexes was investigated through two complementary sets of polymer-electrolyte combinations. In one (series A) the salt was added to the polymer before irradiation, while in the second (series B) the salt was added to a solvent-swelled polymer after irradiation. These experiments were carried out to eliminate the possibility that the presence of LiCF3SO3 during irradiation would affect the ionic conductivity of the final product. Series A and B each consisted of six thin films of I with 0.25 equivalent of LiCF3SO3 per polymer repeat unit.",

author = "Bennett, \{Jordan L.\} and Dembek, \{Alexa A.\} and Allcock, \{Harry R.\} and Heyen, \{Bruce J.\} and Shriver, \{Duward F.\}",

year = "1989",

month = apr,

language = "English (US)",

volume = "30",

pages = "437--438",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

issn = "0032-3934",

number = "1",

note = "Papers Presented at the Dallas, Texas Meeting ; Conference date: 09-04-1989 Through 14-04-1989",

}

Radiation crosslinking of poly[bis-2-(2-methoxyethoxy)ethoxy]phosphazene: effect on solid state ionic conductivity. / Bennett, Jordan L.; Dembek, Alexa A.; Allcock, Harry R. et al.
In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 30, No. 1, 04.1989, p. 437-438.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Radiation crosslinking of poly[bis-2-(2-methoxyethoxy)ethoxy]phosphazene

T2 - Papers Presented at the Dallas, Texas Meeting

AU - Bennett, Jordan L.

AU - Dembek, Alexa A.

AU - Allcock, Harry R.

AU - Heyen, Bruce J.

AU - Shriver, Duward F.

PY - 1989/4

Y1 - 1989/4

N2 - The polyphosphazene, poly[bis(2-2-methoxyethoxy) ethoxy]phosphazene (I), shows excellent promise as a solid electrolyte host when LiCF3SO3 is used as the charge carrier. The ionic conductivity of the gamma irradiated crosslinked polymer/salt complexes was investigated through two complementary sets of polymer-electrolyte combinations. In one (series A) the salt was added to the polymer before irradiation, while in the second (series B) the salt was added to a solvent-swelled polymer after irradiation. These experiments were carried out to eliminate the possibility that the presence of LiCF3SO3 during irradiation would affect the ionic conductivity of the final product. Series A and B each consisted of six thin films of I with 0.25 equivalent of LiCF3SO3 per polymer repeat unit.

AB - The polyphosphazene, poly[bis(2-2-methoxyethoxy) ethoxy]phosphazene (I), shows excellent promise as a solid electrolyte host when LiCF3SO3 is used as the charge carrier. The ionic conductivity of the gamma irradiated crosslinked polymer/salt complexes was investigated through two complementary sets of polymer-electrolyte combinations. In one (series A) the salt was added to the polymer before irradiation, while in the second (series B) the salt was added to a solvent-swelled polymer after irradiation. These experiments were carried out to eliminate the possibility that the presence of LiCF3SO3 during irradiation would affect the ionic conductivity of the final product. Series A and B each consisted of six thin films of I with 0.25 equivalent of LiCF3SO3 per polymer repeat unit.

UR - https://www.scopus.com/pages/publications/0024648708

UR - https://www.scopus.com/pages/publications/0024648708#tab=citedBy

M3 - Conference article

AN - SCOPUS:0024648708

SN - 0032-3934

VL - 30

SP - 437

EP - 438

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

IS - 1

Y2 - 9 April 1989 through 14 April 1989

ER -

Radiation crosslinking of poly[bis-2-(2-methoxyethoxy)ethoxy]phosphazene: effect on solid state ionic conductivity

Abstract

All Science Journal Classification (ASJC) codes

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