Reaction Kinetics of Primary Rock-forming Minerals under Ambient Conditions

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Abstract

Mineral dissolution kinetics influence such phenomena as development of soil fertility, amelioration of the effects of acid rain, formation of karst, acid mine drainage, transport and sequestration of contaminants, sequestration of carbon dioxide at depth in the earth, ore deposition, and metamorphism. On a global basis, mineral weathering kinetics are also involved in the long-term sink for CO2 in the atmosphere: (Formula Presented) CaSiO3 þ CO2 ¼ CaCO3 þ SiO2 ð1Þ MgSiO3 þ CO2 ¼ MgCO3 þ SiO2 ð2Þ These reactions (Urey, 1952) describe the processes that balance the volcanic and metamorphic CO2 production to maintain relatively constant levels of atmospheric CO2 over 105–106 yr timescales. In these equations, Ca- and MgSiO3 represent all calcium- and magnesium-containing silicates. Calcium- and magnesium-silicates at the Earth’s surface are predominantly plagioclase feldspars, Ca–Mg-pyroxenes, amphiboles, and phyllosilicates, Ca–Mg orthosilicates. Although dissolution of the other main rock–forming mineral class, carbonate minerals, does not draw down CO2 from the atmosphere over geologic timescales, carbonate dissolution is globally important in controlling river and ground water chemistry. Despite the importance of mineral dissolution, field weathering rates are generally observed to be up to five orders of magnitude slower than laboratory dissolution rates (White, 1995), and the reason for this discrepancy remains a puzzle. For example, mean lifetimes of 1 mm spheres of rock-forming minerals calculated from measured rate data following Lasaga (1984) are much smaller than the mean half-life of sedimentary rocks (600 My, Garrels and Mackenzie, 1971). As pointed out by others (Velbel,.

Original languageEnglish (US)
Title of host publicationSurface and Ground Water, Weathering, and Soils
PublisherElsevier Inc.
Pages73-117
Number of pages45
Volume5-9
ISBN (Electronic)9780080548074
ISBN (Print)9780080437514
DOIs
StatePublished - Dec 4 2003

All Science Journal Classification (ASJC) codes

  • General Earth and Planetary Sciences

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