Reaction of 2-aminopyrrole and 1-alkyl-2-aminopyrrole with Dmad: Michael addition vs diels-alder reaction

Michael De Rosa; Michelle LaRue; Ian Sellitto; Mark D. Timken

doi:10.1515/HC.2001.7.6.519

Reaction of 2-aminopyrrole and 1-alkyl-2-aminopyrrole with Dmad: Michael addition vs diels-alder reaction

Michael De Rosa
, Michelle LaRue
, Ian Sellitto
, Mark D. Timken

Penn State Brandywine

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

2-Aminopyrrole and 1-substituted-2-aminopyrroles react with DMAD in less than two minutes to give a mixture of E and Z vinyl pyrroles (Michael adducts). No evidence of Diels-Alder cycloaddition was found even at -35°C.

Original language	English (US)
Pages (from-to)	519-520
Number of pages	2
Journal	Heterocyclic Communications
Volume	7
Issue number	6
DOIs	https://doi.org/10.1515/HC.2001.7.6.519
State	Published - 2001

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1515/HC.2001.7.6.519

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title = "Reaction of 2-aminopyrrole and 1-alkyl-2-aminopyrrole with Dmad: Michael addition vs diels-alder reaction",

abstract = "2-Aminopyrrole and 1-substituted-2-aminopyrroles react with DMAD in less than two minutes to give a mixture of E and Z vinyl pyrroles (Michael adducts). No evidence of Diels-Alder cycloaddition was found even at -35°C.",

author = "\{De Rosa\}, Michael and Michelle LaRue and Ian Sellitto and Timken, \{Mark D.\}",

year = "2001",

doi = "10.1515/HC.2001.7.6.519",

language = "English (US)",

volume = "7",

pages = "519--520",

journal = "Heterocyclic Communications",

issn = "0793-0283",

publisher = "Walter de Gruyter GmbH",

number = "6",

}

TY - JOUR

T1 - Reaction of 2-aminopyrrole and 1-alkyl-2-aminopyrrole with Dmad

T2 - Michael addition vs diels-alder reaction

AU - De Rosa, Michael

AU - LaRue, Michelle

AU - Sellitto, Ian

AU - Timken, Mark D.

PY - 2001

Y1 - 2001

N2 - 2-Aminopyrrole and 1-substituted-2-aminopyrroles react with DMAD in less than two minutes to give a mixture of E and Z vinyl pyrroles (Michael adducts). No evidence of Diels-Alder cycloaddition was found even at -35°C.

AB - 2-Aminopyrrole and 1-substituted-2-aminopyrroles react with DMAD in less than two minutes to give a mixture of E and Z vinyl pyrroles (Michael adducts). No evidence of Diels-Alder cycloaddition was found even at -35°C.

UR - https://www.scopus.com/pages/publications/0035566751

UR - https://www.scopus.com/pages/publications/0035566751#tab=citedBy

U2 - 10.1515/HC.2001.7.6.519

DO - 10.1515/HC.2001.7.6.519

M3 - Article

AN - SCOPUS:0035566751

SN - 0793-0283

VL - 7

SP - 519

EP - 520

JO - Heterocyclic Communications

JF - Heterocyclic Communications

IS - 6

ER -

Reaction of 2-aminopyrrole and 1-alkyl-2-aminopyrrole with Dmad: Michael addition vs diels-alder reaction

Abstract

All Science Journal Classification (ASJC) codes

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