Reaction of palladium 1,5-cyclooctadiene alkyl chloride with norbornene derivatives: Relevance to metal-catalyzed addition polymerization of functionalized norbornenes

Myeongsoon Kang; Ayusman Sen

doi:10.1021/om049449h

Reaction of palladium 1,5-cyclooctadiene alkyl chloride with norbornene derivatives: Relevance to metal-catalyzed addition polymerization of functionalized norbornenes

Myeongsoon Kang, Ayusman Sen

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

The insertions of norbornene, bicyclo[2.2.1]-hept-5-ene-endo-2-carboxylic acid ethyl ester, bicyclo-[2.2.1]hept-5-ene-exo-2-carboxylic acid ethyl ester, and bicyclo[2.2.1]hept-5-enyl-endo-2-methyl acetate into the palladium-methyl bond of(η ⁴-cycloocta-1,5-diene)chloromethylpalladium(II) were found to proceed at similar rates, with the product in every case being derived from insertion through the exo face.

Original language	English (US)
Pages (from-to)	5396-5398
Number of pages	3
Journal	Organometallics
Volume	23
Issue number	23
DOIs	https://doi.org/10.1021/om049449h
State	Published - Nov 8 2004

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om049449h

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title = "Reaction of palladium 1,5-cyclooctadiene alkyl chloride with norbornene derivatives: Relevance to metal-catalyzed addition polymerization of functionalized norbornenes",

abstract = "The insertions of norbornene, bicyclo[2.2.1]-hept-5-ene-endo-2-carboxylic acid ethyl ester, bicyclo-[2.2.1]hept-5-ene-exo-2-carboxylic acid ethyl ester, and bicyclo[2.2.1]hept-5-enyl-endo-2-methyl acetate into the palladium-methyl bond of(η 4-cycloocta-1,5-diene)chloromethylpalladium(II) were found to proceed at similar rates, with the product in every case being derived from insertion through the exo face.",

author = "Myeongsoon Kang and Ayusman Sen",

year = "2004",

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doi = "10.1021/om049449h",

language = "English (US)",

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journal = "Organometallics",

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T1 - Reaction of palladium 1,5-cyclooctadiene alkyl chloride with norbornene derivatives

T2 - Relevance to metal-catalyzed addition polymerization of functionalized norbornenes

AU - Kang, Myeongsoon

AU - Sen, Ayusman

PY - 2004/11/8

Y1 - 2004/11/8

N2 - The insertions of norbornene, bicyclo[2.2.1]-hept-5-ene-endo-2-carboxylic acid ethyl ester, bicyclo-[2.2.1]hept-5-ene-exo-2-carboxylic acid ethyl ester, and bicyclo[2.2.1]hept-5-enyl-endo-2-methyl acetate into the palladium-methyl bond of(η 4-cycloocta-1,5-diene)chloromethylpalladium(II) were found to proceed at similar rates, with the product in every case being derived from insertion through the exo face.

AB - The insertions of norbornene, bicyclo[2.2.1]-hept-5-ene-endo-2-carboxylic acid ethyl ester, bicyclo-[2.2.1]hept-5-ene-exo-2-carboxylic acid ethyl ester, and bicyclo[2.2.1]hept-5-enyl-endo-2-methyl acetate into the palladium-methyl bond of(η 4-cycloocta-1,5-diene)chloromethylpalladium(II) were found to proceed at similar rates, with the product in every case being derived from insertion through the exo face.

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ER -

Reaction of palladium 1,5-cyclooctadiene alkyl chloride with norbornene derivatives: Relevance to metal-catalyzed addition polymerization of functionalized norbornenes

Abstract

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