Reaction of the (111) Faces of Single-Crystal Indium Phosphide with Alkylating Agents: Evidence for Selective Reaction of the P-Rich Face

Alan M. Spool; Karen A. Daube; Thomas E. Mallouk; James A. Belmont; Mark S. Wrighton

doi:10.1021/ja00271a083

Reaction of the (111) Faces of Single-Crystal Indium Phosphide with Alkylating Agents: Evidence for Selective Reaction of the P-Rich Face

Alan M. Spool, Karen A. Daube, Thomas E. Mallouk, James A. Belmont, Mark S. Wrighton

Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

We wish to report that the P-rich, (111)B, face of single-crystal InP, but not the In-rich, (111)A, face of the same crystal, reacts with molecular reagents I and II to yield surface-bound material derived from the apparent alkylation of a surface P atom. Exploitation of surface functional groups has been demonstrated to be very important in the attachment of molecular reagents and polymers to electrode surfaces.

Original language	English (US)
Pages (from-to)	3155-3157
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	108
Issue number	11
DOIs	https://doi.org/10.1021/ja00271a083
State	Published - Jan 1 1986

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja00271a083

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abstract = "We wish to report that the P-rich, (111)B, face of single-crystal InP, but not the In-rich, (111)A, face of the same crystal, reacts with molecular reagents I and II to yield surface-bound material derived from the apparent alkylation of a surface P atom. Exploitation of surface functional groups has been demonstrated to be very important in the attachment of molecular reagents and polymers to electrode surfaces.",

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AU - Daube, Karen A.

AU - Mallouk, Thomas E.

AU - Belmont, James A.

AU - Wrighton, Mark S.

PY - 1986/1/1

Y1 - 1986/1/1

N2 - We wish to report that the P-rich, (111)B, face of single-crystal InP, but not the In-rich, (111)A, face of the same crystal, reacts with molecular reagents I and II to yield surface-bound material derived from the apparent alkylation of a surface P atom. Exploitation of surface functional groups has been demonstrated to be very important in the attachment of molecular reagents and polymers to electrode surfaces.

AB - We wish to report that the P-rich, (111)B, face of single-crystal InP, but not the In-rich, (111)A, face of the same crystal, reacts with molecular reagents I and II to yield surface-bound material derived from the apparent alkylation of a surface P atom. Exploitation of surface functional groups has been demonstrated to be very important in the attachment of molecular reagents and polymers to electrode surfaces.

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Reaction of the (111) Faces of Single-Crystal Indium Phosphide with Alkylating Agents: Evidence for Selective Reaction of the P-Rich Face

Abstract

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