TY - JOUR
T1 - Real-time noise reduction for Mössbauer spectroscopy through online implementation of a modified Kalman filter
AU - Abrecht, David G.
AU - Schwantes, Jon M.
AU - Kukkadapu, Ravi K.
AU - McDonald, Benjamin S.
AU - Eiden, Gregory C.
AU - Sweet, Lucas E.
N1 - Publisher Copyright:
© 2014 Elsevier B.V. All rights reserved.
PY - 2015/2/11
Y1 - 2015/2/11
N2 - Spectrum-processing software that incorporates a Gaussian smoothing kernel within the statistics of first-order Kalman filtration has been developed to provide cross-channel spectral noise reduction for increased real-time signal-to-noise ratios for Mössbauer spectroscopy. The filter was optimized for the breadth of the Gaussian using the Mössbauer spectrum of natural iron foil, and comparisons among the peak broadening, signal-to-noise ratios, and shifts in the calculated hyperfine parameters are presented. The results of optimization give a maximum improvement in the signal-to-noise ratio of 51.1% over the unfiltered spectrum at a Gaussian breadth of 27 channels, or 2.5% of the total spectrum width. The full-width half-maximum of the spectrum peaks showed an increase of 19.6% at this optimum point, indicating a relatively weak increase in the peak broadening relative to the signal enhancement, leading to an overall increase in the observable signal. Calculations of the hyperfine parameters showed that no statistically significant deviations were introduced from the application of the filter, confirming the utility of this filter for spectroscopy applications.
AB - Spectrum-processing software that incorporates a Gaussian smoothing kernel within the statistics of first-order Kalman filtration has been developed to provide cross-channel spectral noise reduction for increased real-time signal-to-noise ratios for Mössbauer spectroscopy. The filter was optimized for the breadth of the Gaussian using the Mössbauer spectrum of natural iron foil, and comparisons among the peak broadening, signal-to-noise ratios, and shifts in the calculated hyperfine parameters are presented. The results of optimization give a maximum improvement in the signal-to-noise ratio of 51.1% over the unfiltered spectrum at a Gaussian breadth of 27 channels, or 2.5% of the total spectrum width. The full-width half-maximum of the spectrum peaks showed an increase of 19.6% at this optimum point, indicating a relatively weak increase in the peak broadening relative to the signal enhancement, leading to an overall increase in the observable signal. Calculations of the hyperfine parameters showed that no statistically significant deviations were introduced from the application of the filter, confirming the utility of this filter for spectroscopy applications.
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U2 - 10.1016/j.nima.2014.10.053
DO - 10.1016/j.nima.2014.10.053
M3 - Article
AN - SCOPUS:84919392728
SN - 0168-9002
VL - 773
SP - 66
EP - 71
JO - Nuclear Instruments and Methods in Physics Research, Section A: Accelerators, Spectrometers, Detectors and Associated Equipment
JF - Nuclear Instruments and Methods in Physics Research, Section A: Accelerators, Spectrometers, Detectors and Associated Equipment
ER -