Recent advance in shape-selective catalysis over zeolites for synthesis of specialty chemicals

Chunshan Song

doi:10.1016/s0167-2991(98)80283-8

Recent advance in shape-selective catalysis over zeolites for synthesis of specialty chemicals

Chunshan Song

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

This paper discusses the application of zeolite catalysts for shape-selective conversion of 2-ring and 3-ring polycyclic hydrocarbons into value-added intermediates for making specialty chemicals and monomers of new polymer materials such as advanced engineering plastics, polyester fibers and films, and liquid crystalline polymers. Specifically, we will discuss the new developments in the following reactions over large-pore zeolite catalysts: 1) ring-shift isomerization of phenanthrene derivatives to anthracene derivatives; 2) shape-selective alkylation of naphthalene; 3) shape-selective alkylation of biphenyl; 4) conformational isomerization of cis-decahydronaphthalene into trans-decahydronaphthalene; and 5) shape-selective hydrogenation of naphthalene.

Original language	English (US)
Pages (from-to)	163-186
Number of pages	24
Journal	Studies in Surface Science and Catalysis
Volume	113
DOIs	https://doi.org/10.1016/s0167-2991(98)80283-8
State	Published - 1998

All Science Journal Classification (ASJC) codes

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/s0167-2991(98)80283-8

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title = "Recent advance in shape-selective catalysis over zeolites for synthesis of specialty chemicals",

abstract = "This paper discusses the application of zeolite catalysts for shape-selective conversion of 2-ring and 3-ring polycyclic hydrocarbons into value-added intermediates for making specialty chemicals and monomers of new polymer materials such as advanced engineering plastics, polyester fibers and films, and liquid crystalline polymers. Specifically, we will discuss the new developments in the following reactions over large-pore zeolite catalysts: 1) ring-shift isomerization of phenanthrene derivatives to anthracene derivatives; 2) shape-selective alkylation of naphthalene; 3) shape-selective alkylation of biphenyl; 4) conformational isomerization of cis-decahydronaphthalene into trans-decahydronaphthalene; and 5) shape-selective hydrogenation of naphthalene.",

author = "Chunshan Song",

note = "Funding Information: The author is very grateful to Prof. Harold Schobert of PSU for his encouragement and support and many helpful discussions, and to his coworkers whose names appear in the papers cited. He also thanks Prof. Paul B. Weisz of PSU, Dr. Werner O. Haag of Mobil, Prof. Yoshihiro Sugi of Gifu University, Japan, and Drs. W.-C. Lai, A. Schmitz, and K. M. Reddy of PSU for useful discussions. Various portions of our research were supported through funding or donations of special samples from the U.S. Department of Energy Pittsburgh Energy Technology Center, U.S. Air Force Wright Laboratories, Air Products and Chemicals Inc., and PQ Co.",

year = "1998",

doi = "10.1016/s0167-2991(98)80283-8",

language = "English (US)",

volume = "113",

pages = "163--186",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier Inc.",

}

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T1 - Recent advance in shape-selective catalysis over zeolites for synthesis of specialty chemicals

AU - Song, Chunshan

N1 - Funding Information: The author is very grateful to Prof. Harold Schobert of PSU for his encouragement and support and many helpful discussions, and to his coworkers whose names appear in the papers cited. He also thanks Prof. Paul B. Weisz of PSU, Dr. Werner O. Haag of Mobil, Prof. Yoshihiro Sugi of Gifu University, Japan, and Drs. W.-C. Lai, A. Schmitz, and K. M. Reddy of PSU for useful discussions. Various portions of our research were supported through funding or donations of special samples from the U.S. Department of Energy Pittsburgh Energy Technology Center, U.S. Air Force Wright Laboratories, Air Products and Chemicals Inc., and PQ Co.

PY - 1998

Y1 - 1998

N2 - This paper discusses the application of zeolite catalysts for shape-selective conversion of 2-ring and 3-ring polycyclic hydrocarbons into value-added intermediates for making specialty chemicals and monomers of new polymer materials such as advanced engineering plastics, polyester fibers and films, and liquid crystalline polymers. Specifically, we will discuss the new developments in the following reactions over large-pore zeolite catalysts: 1) ring-shift isomerization of phenanthrene derivatives to anthracene derivatives; 2) shape-selective alkylation of naphthalene; 3) shape-selective alkylation of biphenyl; 4) conformational isomerization of cis-decahydronaphthalene into trans-decahydronaphthalene; and 5) shape-selective hydrogenation of naphthalene.

AB - This paper discusses the application of zeolite catalysts for shape-selective conversion of 2-ring and 3-ring polycyclic hydrocarbons into value-added intermediates for making specialty chemicals and monomers of new polymer materials such as advanced engineering plastics, polyester fibers and films, and liquid crystalline polymers. Specifically, we will discuss the new developments in the following reactions over large-pore zeolite catalysts: 1) ring-shift isomerization of phenanthrene derivatives to anthracene derivatives; 2) shape-selective alkylation of naphthalene; 3) shape-selective alkylation of biphenyl; 4) conformational isomerization of cis-decahydronaphthalene into trans-decahydronaphthalene; and 5) shape-selective hydrogenation of naphthalene.

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DO - 10.1016/s0167-2991(98)80283-8

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SN - 0167-2991

VL - 113

SP - 163

EP - 186

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Recent advance in shape-selective catalysis over zeolites for synthesis of specialty chemicals

Abstract

All Science Journal Classification (ASJC) codes

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