Ruthenium-catalyzed knoevenagel condensation: A new route toward cyano-substituted poly(p-phenylenevinylene)s

Jian Liao; Qing Wang

doi:10.1021/ma049243s

Ruthenium-catalyzed knoevenagel condensation: A new route toward cyano-substituted poly(p-phenylenevinylene)s

Jian Liao, Qing Wang

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26 Scopus citations

Abstract

The ruthenium-catalyzed Knoevenagel reaction was developed for the preparation of cyano-substituted conjugated polymers. The polymerization was quenched by pouring the reaction mixture into methanol. The structures of polymers were confirmed by spectroscopic studies and elemental analysis. The results show that Knoevenagel polycondensation mediated by transition metal complexes enjoys the advantages of neutral and mild reaction conditions.

Original language	English (US)
Pages (from-to)	7061-7063
Number of pages	3
Journal	Macromolecules
Volume	37
Issue number	18
DOIs	https://doi.org/10.1021/ma049243s
State	Published - Sep 7 2004

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma049243s

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title = "Ruthenium-catalyzed knoevenagel condensation: A new route toward cyano-substituted poly(p-phenylenevinylene)s",

abstract = "The ruthenium-catalyzed Knoevenagel reaction was developed for the preparation of cyano-substituted conjugated polymers. The polymerization was quenched by pouring the reaction mixture into methanol. The structures of polymers were confirmed by spectroscopic studies and elemental analysis. The results show that Knoevenagel polycondensation mediated by transition metal complexes enjoys the advantages of neutral and mild reaction conditions.",

author = "Jian Liao and Qing Wang",

year = "2004",

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doi = "10.1021/ma049243s",

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AU - Liao, Jian

AU - Wang, Qing

PY - 2004/9/7

Y1 - 2004/9/7

N2 - The ruthenium-catalyzed Knoevenagel reaction was developed for the preparation of cyano-substituted conjugated polymers. The polymerization was quenched by pouring the reaction mixture into methanol. The structures of polymers were confirmed by spectroscopic studies and elemental analysis. The results show that Knoevenagel polycondensation mediated by transition metal complexes enjoys the advantages of neutral and mild reaction conditions.

AB - The ruthenium-catalyzed Knoevenagel reaction was developed for the preparation of cyano-substituted conjugated polymers. The polymerization was quenched by pouring the reaction mixture into methanol. The structures of polymers were confirmed by spectroscopic studies and elemental analysis. The results show that Knoevenagel polycondensation mediated by transition metal complexes enjoys the advantages of neutral and mild reaction conditions.

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Ruthenium-catalyzed knoevenagel condensation: A new route toward cyano-substituted poly(p-phenylenevinylene)s

Abstract

All Science Journal Classification (ASJC) codes

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