Seeking a Au-C stretch on gold nanoparticles with 13C-labeled N-heterocyclic carbenes

Isabel M. Jensen; Shayanta Chowdhury; Gaohe Hu; Lasse Jensen; Jon P. Camden; David M. Jenkins

doi:10.1039/d3cc04973f

Seeking a Au-C stretch on gold nanoparticles with ¹³C-labeled N-heterocyclic carbenes

Isabel M. Jensen, Shayanta Chowdhury, Gaohe Hu, Lasse Jensen, Jon P. Camden, David M. Jenkins

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Gold nanoparticles were functionalized with natural abundance and ¹³C-labeled N-heterocyclic carbenes (NHCs) to investigate the Au-C stretch. A combinatorial approach of surface enhanced Raman spectroscopy (SERS) and density-functional theory (DFT) calculations highlighted vibrational modes significantly impacted by isotopic labeling at the carbene carbon. Critically, no isotopically-impacted stretching mode showed majority Au-C character.

Original language	English (US)
Pages (from-to)	14524-14527
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	98
DOIs	https://doi.org/10.1039/d3cc04973f
State	Published - Nov 15 2023

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d3cc04973f

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abstract = "Gold nanoparticles were functionalized with natural abundance and 13C-labeled N-heterocyclic carbenes (NHCs) to investigate the Au-C stretch. A combinatorial approach of surface enhanced Raman spectroscopy (SERS) and density-functional theory (DFT) calculations highlighted vibrational modes significantly impacted by isotopic labeling at the carbene carbon. Critically, no isotopically-impacted stretching mode showed majority Au-C character.",

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AU - Chowdhury, Shayanta

AU - Hu, Gaohe

AU - Jensen, Lasse

AU - Camden, Jon P.

AU - Jenkins, David M.

PY - 2023/11/15

Y1 - 2023/11/15

N2 - Gold nanoparticles were functionalized with natural abundance and 13C-labeled N-heterocyclic carbenes (NHCs) to investigate the Au-C stretch. A combinatorial approach of surface enhanced Raman spectroscopy (SERS) and density-functional theory (DFT) calculations highlighted vibrational modes significantly impacted by isotopic labeling at the carbene carbon. Critically, no isotopically-impacted stretching mode showed majority Au-C character.

AB - Gold nanoparticles were functionalized with natural abundance and 13C-labeled N-heterocyclic carbenes (NHCs) to investigate the Au-C stretch. A combinatorial approach of surface enhanced Raman spectroscopy (SERS) and density-functional theory (DFT) calculations highlighted vibrational modes significantly impacted by isotopic labeling at the carbene carbon. Critically, no isotopically-impacted stretching mode showed majority Au-C character.

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Seeking a Au-C stretch on gold nanoparticles with ¹³C-labeled N-heterocyclic carbenes

Abstract

All Science Journal Classification (ASJC) codes

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