Selective reduction of biomass by hydriodic acid and its in situ regeneration from iodine by metal/hydrogen

Weiran Yang; Matthew R. Grochowski; Ayusman Sen

doi:10.1002/cssc.201100669

Selective reduction of biomass by hydriodic acid and its in situ regeneration from iodine by metal/hydrogen

Weiran Yang, Matthew R. Grochowski, Ayusman Sen

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

HI returns: Hydroiodic acid is a highly selective reducing reagent for a wide variety of substrates. Its application is limited by the formation of iodine and the difficulty in reconverting that iodione back to HI in situ. We report the facile conversion of I₂ to HI by metal-catalyzed hydrogenation in the presence of water, and demonstrate the utility of this process in the conversion of fructose to 5-methyfurfural and glycerol to 2-iodopropane.

Original language	English (US)
Pages (from-to)	1218-1222
Number of pages	5
Journal	ChemSusChem
Volume	5
Issue number	7
DOIs	https://doi.org/10.1002/cssc.201100669
State	Published - Jul 2012

All Science Journal Classification (ASJC) codes

Environmental Chemistry
General Chemical Engineering
General Materials Science
General Energy

Access to Document

10.1002/cssc.201100669

Cite this

@article{cd5a254666614d5e867083b4a59140c1,

title = "Selective reduction of biomass by hydriodic acid and its in situ regeneration from iodine by metal/hydrogen",

abstract = "HI returns: Hydroiodic acid is a highly selective reducing reagent for a wide variety of substrates. Its application is limited by the formation of iodine and the difficulty in reconverting that iodione back to HI in situ. We report the facile conversion of I2 to HI by metal-catalyzed hydrogenation in the presence of water, and demonstrate the utility of this process in the conversion of fructose to 5-methyfurfural and glycerol to 2-iodopropane.",

author = "Weiran Yang and Grochowski, {Matthew R.} and Ayusman Sen",

year = "2012",

month = jul,

doi = "10.1002/cssc.201100669",

language = "English (US)",

volume = "5",

pages = "1218--1222",

journal = "ChemSusChem",

issn = "1864-5631",

publisher = "Wiley-VCH Verlag",

number = "7",

}

TY - JOUR

T1 - Selective reduction of biomass by hydriodic acid and its in situ regeneration from iodine by metal/hydrogen

AU - Yang, Weiran

AU - Grochowski, Matthew R.

AU - Sen, Ayusman

PY - 2012/7

Y1 - 2012/7

N2 - HI returns: Hydroiodic acid is a highly selective reducing reagent for a wide variety of substrates. Its application is limited by the formation of iodine and the difficulty in reconverting that iodione back to HI in situ. We report the facile conversion of I2 to HI by metal-catalyzed hydrogenation in the presence of water, and demonstrate the utility of this process in the conversion of fructose to 5-methyfurfural and glycerol to 2-iodopropane.

AB - HI returns: Hydroiodic acid is a highly selective reducing reagent for a wide variety of substrates. Its application is limited by the formation of iodine and the difficulty in reconverting that iodione back to HI in situ. We report the facile conversion of I2 to HI by metal-catalyzed hydrogenation in the presence of water, and demonstrate the utility of this process in the conversion of fructose to 5-methyfurfural and glycerol to 2-iodopropane.

UR - http://www.scopus.com/inward/record.url?scp=84863665610&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84863665610&partnerID=8YFLogxK

U2 - 10.1002/cssc.201100669

DO - 10.1002/cssc.201100669

M3 - Article

C2 - 22492614

AN - SCOPUS:84863665610

SN - 1864-5631

VL - 5

SP - 1218

EP - 1222

JO - ChemSusChem

JF - ChemSusChem

IS - 7

ER -

Selective reduction of biomass by hydriodic acid and its in situ regeneration from iodine by metal/hydrogen

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this