Selectivity in near-diffusion-limited reactions. Isotope effects in phosphorylnitrene insertion into CH bonds.

Przemyslaw Maslak; John J. Sczepanski; Robert D. Minard; Linda A. Collins

doi:10.1016/S0040-4039(00)97595-6

Selectivity in near-diffusion-limited reactions. Isotope effects in phosphorylnitrene insertion into CH bonds.

Przemyslaw Maslak
, John J. Sczepanski
, Robert D. Minard
, Linda A. Collins

Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

In near-diffusion-limited reactions the apparent selectivity of reactive intermediates measured in intermolecular competition experiments is a function of the intrinsic selectivity and the ratio of the reaction rate to the diffusion controlled rate. This dependence can be used to test for diffusion limited reactions as demonstrated by measurements of isotope effects for CH insertion of phosphorylnitrenes.

Original language	English (US)
Pages (from-to)	4261-4264
Number of pages	4
Journal	Tetrahedron Letters
Volume	31
Issue number	30
DOIs	https://doi.org/10.1016/S0040-4039(00)97595-6
State	Published - 1990

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)97595-6

Cite this

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title = "Selectivity in near-diffusion-limited reactions. Isotope effects in phosphorylnitrene insertion into CH bonds.",

abstract = "In near-diffusion-limited reactions the apparent selectivity of reactive intermediates measured in intermolecular competition experiments is a function of the intrinsic selectivity and the ratio of the reaction rate to the diffusion controlled rate. This dependence can be used to test for diffusion limited reactions as demonstrated by measurements of isotope effects for CH insertion of phosphorylnitrenes.",

author = "Przemyslaw Maslak and Sczepanski, \{John J.\} and Minard, \{Robert D.\} and Collins, \{Linda A.\}",

year = "1990",

doi = "10.1016/S0040-4039(00)97595-6",

language = "English (US)",

volume = "31",

pages = "4261--4264",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "30",

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T1 - Selectivity in near-diffusion-limited reactions. Isotope effects in phosphorylnitrene insertion into CH bonds.

AU - Maslak, Przemyslaw

AU - Sczepanski, John J.

AU - Minard, Robert D.

AU - Collins, Linda A.

PY - 1990

Y1 - 1990

N2 - In near-diffusion-limited reactions the apparent selectivity of reactive intermediates measured in intermolecular competition experiments is a function of the intrinsic selectivity and the ratio of the reaction rate to the diffusion controlled rate. This dependence can be used to test for diffusion limited reactions as demonstrated by measurements of isotope effects for CH insertion of phosphorylnitrenes.

AB - In near-diffusion-limited reactions the apparent selectivity of reactive intermediates measured in intermolecular competition experiments is a function of the intrinsic selectivity and the ratio of the reaction rate to the diffusion controlled rate. This dependence can be used to test for diffusion limited reactions as demonstrated by measurements of isotope effects for CH insertion of phosphorylnitrenes.

UR - https://www.scopus.com/pages/publications/0025364918

UR - https://www.scopus.com/pages/publications/0025364918#tab=citedBy

U2 - 10.1016/S0040-4039(00)97595-6

DO - 10.1016/S0040-4039(00)97595-6

M3 - Article

AN - SCOPUS:0025364918

SN - 0040-4039

VL - 31

SP - 4261

EP - 4264

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 30

ER -

Selectivity in near-diffusion-limited reactions. Isotope effects in phosphorylnitrene insertion into CH bonds.

Abstract

All Science Journal Classification (ASJC) codes

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