Self-assembly of mesostructured conjugated poly(2,5-thienylene ethynylene)/silica nanocomposites

Byron McCaughey; Chris Costello; Donghai Wang; J. Eric Hampsey; Zhenzhong Yang; Chaojun Li; C. Jeffrey Brinker; Yunfeng Lu

doi:10.1002/adma.200304931

Self-assembly of mesostructured conjugated poly(2,5-thienylene ethynylene)/silica nanocomposites

Byron McCaughey, Chris Costello, Donghai Wang, J. Eric Hampsey, Zhenzhong Yang, Chaojun Li, C. Jeffrey Brinker, Yunfeng Lu

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The formation of conjugated PTE/silica nanocomposites was demonstrated by a novel sol-gel self-assembly and an air- and water-insensitive organometallic-catalyzed polymerization method. The robustness of this synthesis was further demonstrated by the ability of the oligomeric PTE thin films to continuously react with acetylene gas that results in darkened films with increased UV-vis absorptions. This approach provides a unique and ready route to synthesize nanostructured conjugated polymer and composites.

Original language	English (US)
Pages (from-to)	1266-1269
Number of pages	4
Journal	Advanced Materials
Volume	15
Issue number	15
DOIs	https://doi.org/10.1002/adma.200304931
State	Published - Aug 5 2003

All Science Journal Classification (ASJC) codes

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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title = "Self-assembly of mesostructured conjugated poly(2,5-thienylene ethynylene)/silica nanocomposites",

abstract = "The formation of conjugated PTE/silica nanocomposites was demonstrated by a novel sol-gel self-assembly and an air- and water-insensitive organometallic-catalyzed polymerization method. The robustness of this synthesis was further demonstrated by the ability of the oligomeric PTE thin films to continuously react with acetylene gas that results in darkened films with increased UV-vis absorptions. This approach provides a unique and ready route to synthesize nanostructured conjugated polymer and composites.",

author = "Byron McCaughey and Chris Costello and Donghai Wang and Hampsey, {J. Eric} and Zhenzhong Yang and Chaojun Li and Brinker, {C. Jeffrey} and Yunfeng Lu",

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doi = "10.1002/adma.200304931",

language = "English (US)",

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T1 - Self-assembly of mesostructured conjugated poly(2,5-thienylene ethynylene)/silica nanocomposites

AU - McCaughey, Byron

AU - Costello, Chris

AU - Wang, Donghai

AU - Hampsey, J. Eric

AU - Yang, Zhenzhong

AU - Li, Chaojun

AU - Brinker, C. Jeffrey

AU - Lu, Yunfeng

PY - 2003/8/5

Y1 - 2003/8/5

N2 - The formation of conjugated PTE/silica nanocomposites was demonstrated by a novel sol-gel self-assembly and an air- and water-insensitive organometallic-catalyzed polymerization method. The robustness of this synthesis was further demonstrated by the ability of the oligomeric PTE thin films to continuously react with acetylene gas that results in darkened films with increased UV-vis absorptions. This approach provides a unique and ready route to synthesize nanostructured conjugated polymer and composites.

AB - The formation of conjugated PTE/silica nanocomposites was demonstrated by a novel sol-gel self-assembly and an air- and water-insensitive organometallic-catalyzed polymerization method. The robustness of this synthesis was further demonstrated by the ability of the oligomeric PTE thin films to continuously react with acetylene gas that results in darkened films with increased UV-vis absorptions. This approach provides a unique and ready route to synthesize nanostructured conjugated polymer and composites.

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U2 - 10.1002/adma.200304931

DO - 10.1002/adma.200304931

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VL - 15

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EP - 1269

JO - Advanced Materials

JF - Advanced Materials

IS - 15

ER -

Self-assembly of mesostructured conjugated poly(2,5-thienylene ethynylene)/silica nanocomposites

Abstract

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