Semiclassical model for the distribution of final polar angles and m′ states in rotationally inelastic collisions

T. J. Price, A. C. Towne, D. Talbi, A. P. Hickman

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Using the venerable vector model, we develop an expression for the change in the polar angle of the angular momentum of a rotator caused by collisions in a cell-type experiment. For an initial j precessing with polar angle θ, and a given distribution of 'tipping angles', we derive the distribution of final polar angles θ′. Final m′ levels are also determined. The results agree well with exact quantum calculations for thermal collisions of He or Ar with NaK. We also identify a special case where the distribution of θ′ has a simple Lorentzian form.

Original languageEnglish (US)
Pages (from-to)180-186
Number of pages7
JournalChemical Physics Letters
Volume645
DOIs
StatePublished - Feb 2016

All Science Journal Classification (ASJC) codes

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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