Shear and salt effects on the structure of MCM-41 synthesis gels

Karen J. Edler; Philip A. Reynolds; Anthony S. Brown; Tania M. Slawecki; John W. White

doi:10.1039/a707394a

Shear and salt effects on the structure of MCM-41 synthesis gels

Karen J. Edler, Philip A. Reynolds, Anthony S. Brown, Tania M. Slawecki, John W. White

Materials Research Institute (MRI)

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Orientational ordering under shear was observed for some precursor gels for the synthesis of the hexagonal mesoporous silica MCM-41 in the presence of high KBr concentrations. The presence of KBr disrupted the formation of the first-order MCM-41 diffraction peak dependent upon KBr concentration. Synthesis gels which formed good quality MCM-41, but with no added KBr salt, were not oriented by strong shearing. In addition MCM-41 formed without shear and salt was not disrupted by subsequent shearing.

Original language	English (US)
Pages (from-to)	1287-1291
Number of pages	5
Journal	Journal of the Chemical Society - Faraday Transactions
Volume	94
Issue number	9
DOIs	https://doi.org/10.1039/a707394a
State	Published - 1998

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry

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10.1039/a707394a

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title = "Shear and salt effects on the structure of MCM-41 synthesis gels",

abstract = "Orientational ordering under shear was observed for some precursor gels for the synthesis of the hexagonal mesoporous silica MCM-41 in the presence of high KBr concentrations. The presence of KBr disrupted the formation of the first-order MCM-41 diffraction peak dependent upon KBr concentration. Synthesis gels which formed good quality MCM-41, but with no added KBr salt, were not oriented by strong shearing. In addition MCM-41 formed without shear and salt was not disrupted by subsequent shearing.",

author = "Edler, {Karen J.} and Reynolds, {Philip A.} and Brown, {Anthony S.} and Slawecki, {Tania M.} and White, {John W.}",

year = "1998",

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volume = "94",

pages = "1287--1291",

journal = "Journal of the Chemical Society - Faraday Transactions",

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T1 - Shear and salt effects on the structure of MCM-41 synthesis gels

AU - Edler, Karen J.

AU - Reynolds, Philip A.

AU - Brown, Anthony S.

AU - Slawecki, Tania M.

AU - White, John W.

PY - 1998

Y1 - 1998

N2 - Orientational ordering under shear was observed for some precursor gels for the synthesis of the hexagonal mesoporous silica MCM-41 in the presence of high KBr concentrations. The presence of KBr disrupted the formation of the first-order MCM-41 diffraction peak dependent upon KBr concentration. Synthesis gels which formed good quality MCM-41, but with no added KBr salt, were not oriented by strong shearing. In addition MCM-41 formed without shear and salt was not disrupted by subsequent shearing.

AB - Orientational ordering under shear was observed for some precursor gels for the synthesis of the hexagonal mesoporous silica MCM-41 in the presence of high KBr concentrations. The presence of KBr disrupted the formation of the first-order MCM-41 diffraction peak dependent upon KBr concentration. Synthesis gels which formed good quality MCM-41, but with no added KBr salt, were not oriented by strong shearing. In addition MCM-41 formed without shear and salt was not disrupted by subsequent shearing.

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JO - Journal of the Chemical Society - Faraday Transactions

JF - Journal of the Chemical Society - Faraday Transactions

IS - 9

ER -

Shear and salt effects on the structure of MCM-41 synthesis gels

Abstract

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