Silver nitrate-high pressure liquid chromatography of geometrical isomers

R. R. Heath; J. H. Tumlinson; R. E. Doolittle; Adron T. Proveaux

doi:10.1093/chromsci/13.8.380

Silver nitrate-high pressure liquid chromatography of geometrical isomers

R. R. Heath, J. H. Tumlinson, R. E. Doolittle, Adron T. Proveaux

Entomology

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Abstract

Rapid, highly efficient preparative liquid chromatographic separations of geometrical isomers of unsaturated acetates, aldehydes, and hydrocarbons were obtained with silver nitrate coated on silica gel. When benzene was used, the compounds eluted in a reasonable time and the columns could be reused since they showed no significant deterioration. Silica gel of three ranges of partical size treated with AgN0₃ in our laboratory produced lower operating pressures and better peak shape than commercially obtained AgN0₃-silica.

Original language	English (US)
Pages (from-to)	380-382
Number of pages	3
Journal	Journal of Chromatographic Science
Volume	13
Issue number	8
DOIs	https://doi.org/10.1093/chromsci/13.8.380
State	Published - Aug 1975

All Science Journal Classification (ASJC) codes

Analytical Chemistry

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10.1093/chromsci/13.8.380

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year = "1975",

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AU - Tumlinson, J. H.

AU - Doolittle, R. E.

AU - Proveaux, Adron T.

PY - 1975/8

Y1 - 1975/8

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AB - Rapid, highly efficient preparative liquid chromatographic separations of geometrical isomers of unsaturated acetates, aldehydes, and hydrocarbons were obtained with silver nitrate coated on silica gel. When benzene was used, the compounds eluted in a reasonable time and the columns could be reused since they showed no significant deterioration. Silica gel of three ranges of partical size treated with AgN03 in our laboratory produced lower operating pressures and better peak shape than commercially obtained AgN03-silica.

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Silver nitrate-high pressure liquid chromatography of geometrical isomers

Abstract

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