Simplified chemical-physical theory for liquid metal solutions-I. Temperature dependence of the gibbs energy

Montgomery M. Alger; Charles A. Eckert

doi:10.1016/0009-2509(86)80014-8

Simplified chemical-physical theory for liquid metal solutions-I. Temperature dependence of the gibbs energy

Montgomery M. Alger, Charles A. Eckert

Chemical Engineering

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6 Scopus citations

Abstract

The thermodynamic functions of Group IIB-VA systems Cd-Bi, Cd-Sb and Zn-Sb are modelled with a simplified chemical-physical theory model. Positive and negative deviations from ideal mixing behaviour are calculated with the model. Compounds of fixed stoichiometry are assumed in the liquid phase, with interatomic interactions represented by the Scatchard equation. Expressions for the enthalpy of mixing and mixture heat capacity are derived from the Gibbs energy and expressed in terms of model parameters.

Original language	English (US)
Pages (from-to)	2829-2837
Number of pages	9
Journal	Chemical Engineering Science
Volume	41
Issue number	11
DOIs	https://doi.org/10.1016/0009-2509(86)80014-8
State	Published - 1986

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

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title = "Simplified chemical-physical theory for liquid metal solutions-I. Temperature dependence of the gibbs energy",

abstract = "The thermodynamic functions of Group IIB-VA systems Cd-Bi, Cd-Sb and Zn-Sb are modelled with a simplified chemical-physical theory model. Positive and negative deviations from ideal mixing behaviour are calculated with the model. Compounds of fixed stoichiometry are assumed in the liquid phase, with interatomic interactions represented by the Scatchard equation. Expressions for the enthalpy of mixing and mixture heat capacity are derived from the Gibbs energy and expressed in terms of model parameters.",

author = "Alger, {Montgomery M.} and Eckert, {Charles A.}",

year = "1986",

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T1 - Simplified chemical-physical theory for liquid metal solutions-I. Temperature dependence of the gibbs energy

AU - Alger, Montgomery M.

AU - Eckert, Charles A.

PY - 1986

Y1 - 1986

N2 - The thermodynamic functions of Group IIB-VA systems Cd-Bi, Cd-Sb and Zn-Sb are modelled with a simplified chemical-physical theory model. Positive and negative deviations from ideal mixing behaviour are calculated with the model. Compounds of fixed stoichiometry are assumed in the liquid phase, with interatomic interactions represented by the Scatchard equation. Expressions for the enthalpy of mixing and mixture heat capacity are derived from the Gibbs energy and expressed in terms of model parameters.

AB - The thermodynamic functions of Group IIB-VA systems Cd-Bi, Cd-Sb and Zn-Sb are modelled with a simplified chemical-physical theory model. Positive and negative deviations from ideal mixing behaviour are calculated with the model. Compounds of fixed stoichiometry are assumed in the liquid phase, with interatomic interactions represented by the Scatchard equation. Expressions for the enthalpy of mixing and mixture heat capacity are derived from the Gibbs energy and expressed in terms of model parameters.

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JO - Chemical Engineering Science

JF - Chemical Engineering Science

IS - 11

ER -

Simplified chemical-physical theory for liquid metal solutions-I. Temperature dependence of the gibbs energy

Abstract

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