Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation

Saravanakumar T. Pillai; Tom Fischer; Tyler T. Clikeman; Jennifer Esbenshade; Catherine G P. Berdanier; Heather Rohwer; Mark Jastram; Wonjun Kang; Choumini Balasanthiran; Charles S. Spanjers; Talgat Inerbaev; Dmitri S. Kilin; Robert Martin Rioux, Jr.; James D. Hoefelmeyer

doi:10.1021/bk-2015-1196.ch004

Single Site Metal Ions on the Surface of TiO₂ Nanorods - A Platform for Theoretical and Experimental Investigation

Saravanakumar T. Pillai
, Tom Fischer
, Tyler T. Clikeman
, Jennifer Esbenshade
, Catherine G P. Berdanier
, Heather Rohwer
, Mark Jastram
, Wonjun Kang
, Choumini Balasanthiran
, Charles S. Spanjers
, Talgat Inerbaev
, Dmitri S. Kilin
, Robert Martin Rioux, Jr.
, James D. Hoefelmeyer

Research output: Chapter in Book/Report/Conference proceeding › Chapter

3 Scopus citations

Abstract

We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.

Original language	English (US)
Title of host publication	Photoinduced Processes at Surfaces and in Nanomaterials
Editors	Dmitri Kilin
Publisher	American Chemical Society
Pages	103-116
Number of pages	14
ISBN (Electronic)	9780841230941
DOIs	https://doi.org/10.1021/bk-2015-1196.ch004
State	Published - 2015

Publication series

Name	ACS Symposium Series
Volume	1196
ISSN (Print)	0097-6156
ISSN (Electronic)	1947-5918

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering

Access to Document

10.1021/bk-2015-1196.ch004

Cite this

Pillai, S. T., Fischer, T., Clikeman, T. T., Esbenshade, J., Berdanier, C. G. P., Rohwer, H., Jastram, M., Kang, W., Balasanthiran, C., Spanjers, C. S., Inerbaev, T., Kilin, D. S., Rioux, Jr., R. M., & Hoefelmeyer, J. D. (2015). Single Site Metal Ions on the Surface of TiO₂ Nanorods - A Platform for Theoretical and Experimental Investigation. In D. Kilin (Ed.), Photoinduced Processes at Surfaces and in Nanomaterials (pp. 103-116). (ACS Symposium Series; Vol. 1196). American Chemical Society. https://doi.org/10.1021/bk-2015-1196.ch004

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title = "Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation",

abstract = "We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.",

author = "Pillai, \{Saravanakumar T.\} and Tom Fischer and Clikeman, \{Tyler T.\} and Jennifer Esbenshade and Berdanier, \{Catherine G P.\} and Heather Rohwer and Mark Jastram and Wonjun Kang and Choumini Balasanthiran and Spanjers, \{Charles S.\} and Talgat Inerbaev and Kilin, \{Dmitri S.\} and \{Rioux, Jr.\}, \{Robert Martin\} and Hoefelmeyer, \{James D.\}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

doi = "10.1021/bk-2015-1196.ch004",

language = "English (US)",

series = "ACS Symposium Series",

publisher = "American Chemical Society",

pages = "103--116",

editor = "Dmitri Kilin",

booktitle = "Photoinduced Processes at Surfaces and in Nanomaterials",

address = "United States",

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Pillai, ST, Fischer, T, Clikeman, TT, Esbenshade, J, Berdanier, CGP, Rohwer, H, Jastram, M, Kang, W, Balasanthiran, C, Spanjers, CS, Inerbaev, T, Kilin, DS, Rioux, Jr., RM & Hoefelmeyer, JD 2015, Single Site Metal Ions on the Surface of TiO₂ Nanorods - A Platform for Theoretical and Experimental Investigation. in D Kilin (ed.), Photoinduced Processes at Surfaces and in Nanomaterials. ACS Symposium Series, vol. 1196, American Chemical Society, pp. 103-116. https://doi.org/10.1021/bk-2015-1196.ch004

Single Site Metal Ions on the Surface of TiO₂ Nanorods - A Platform for Theoretical and Experimental Investigation. / Pillai, Saravanakumar T.; Fischer, Tom; Clikeman, Tyler T. et al.
Photoinduced Processes at Surfaces and in Nanomaterials. ed. / Dmitri Kilin. American Chemical Society, 2015. p. 103-116 (ACS Symposium Series; Vol. 1196).

Research output: Chapter in Book/Report/Conference proceeding › Chapter

TY - CHAP

T1 - Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation

AU - Pillai, Saravanakumar T.

AU - Fischer, Tom

AU - Clikeman, Tyler T.

AU - Esbenshade, Jennifer

AU - Berdanier, Catherine G P.

AU - Rohwer, Heather

AU - Jastram, Mark

AU - Kang, Wonjun

AU - Balasanthiran, Choumini

AU - Spanjers, Charles S.

AU - Inerbaev, Talgat

AU - Kilin, Dmitri S.

AU - Rioux, Jr., Robert Martin

AU - Hoefelmeyer, James D.

PY - 2015

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N2 - We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.

AB - We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.

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EP - 116

BT - Photoinduced Processes at Surfaces and in Nanomaterials

A2 - Kilin, Dmitri

PB - American Chemical Society

ER -

Pillai ST, Fischer T, Clikeman TT, Esbenshade J, Berdanier CGP, Rohwer H et al. Single Site Metal Ions on the Surface of TiO₂ Nanorods - A Platform for Theoretical and Experimental Investigation. In Kilin D, editor, Photoinduced Processes at Surfaces and in Nanomaterials. American Chemical Society. 2015. p. 103-116. (ACS Symposium Series). doi: 10.1021/bk-2015-1196.ch004