Solvent effects on host-guest complexation

J. N. Spencer; J. E. Mihalick; I. M. Paul; W. J. Nicholson; T. J. Nicholson; X. Ke; Q. He; F. J. Carter; S. E. Daniels; L. J. Fenton; J. L. Ealy; S. Puppala; C. H. Yoder

doi:10.1007/BF00972717

Solvent effects on host-guest complexation

J. N. Spencer, J. E. Mihalick, I. M. Paul, W. J. Nicholson, T. J. Nicholson, X. Ke, Q. He, F. J. Carter, S. E. Daniels, L. J. Fenton, J. L. Ealy, S. Puppala, C. H. Yoder

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Complex formation between 15-crown-5 and malononitrile was studied in twelve solvents by calorimetry. Thermodynamic parameters for the crown ether adduct were determined and used in a LFER analysis to ascertain the solvent effects on the complexation process. Enthalpy of solution data show that malononitrile is solvated by electron pair donation by the solvents and the crown ether is solvated by donating electron pairs to the solvents. The complex is more solvated than the monomers.

Original language	English (US)
Pages (from-to)	711-720
Number of pages	10
Journal	Journal of Solution Chemistry
Volume	23
Issue number	6
DOIs	https://doi.org/10.1007/BF00972717
State	Published - Jun 1994

All Science Journal Classification (ASJC) codes

Biophysics
Biochemistry
Molecular Biology
Physical and Theoretical Chemistry

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10.1007/BF00972717

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@article{9bfc3b1e924a42c285af8773813f338c,

title = "Solvent effects on host-guest complexation",

abstract = "Complex formation between 15-crown-5 and malononitrile was studied in twelve solvents by calorimetry. Thermodynamic parameters for the crown ether adduct were determined and used in a LFER analysis to ascertain the solvent effects on the complexation process. Enthalpy of solution data show that malononitrile is solvated by electron pair donation by the solvents and the crown ether is solvated by donating electron pairs to the solvents. The complex is more solvated than the monomers.",

author = "Spencer, {J. N.} and Mihalick, {J. E.} and Paul, {I. M.} and Nicholson, {W. J.} and Nicholson, {T. J.} and X. Ke and Q. He and Carter, {F. J.} and Daniels, {S. E.} and Fenton, {L. J.} and Ealy, {J. L.} and S. Puppala and Yoder, {C. H.}",

year = "1994",

month = jun,

doi = "10.1007/BF00972717",

language = "English (US)",

volume = "23",

pages = "711--720",

journal = "Journal of Solution Chemistry",

issn = "0095-9782",

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number = "6",

}

TY - JOUR

T1 - Solvent effects on host-guest complexation

AU - Spencer, J. N.

AU - Mihalick, J. E.

AU - Paul, I. M.

AU - Nicholson, W. J.

AU - Nicholson, T. J.

AU - Ke, X.

AU - He, Q.

AU - Carter, F. J.

AU - Daniels, S. E.

AU - Fenton, L. J.

AU - Ealy, J. L.

AU - Puppala, S.

AU - Yoder, C. H.

PY - 1994/6

Y1 - 1994/6

N2 - Complex formation between 15-crown-5 and malononitrile was studied in twelve solvents by calorimetry. Thermodynamic parameters for the crown ether adduct were determined and used in a LFER analysis to ascertain the solvent effects on the complexation process. Enthalpy of solution data show that malononitrile is solvated by electron pair donation by the solvents and the crown ether is solvated by donating electron pairs to the solvents. The complex is more solvated than the monomers.

AB - Complex formation between 15-crown-5 and malononitrile was studied in twelve solvents by calorimetry. Thermodynamic parameters for the crown ether adduct were determined and used in a LFER analysis to ascertain the solvent effects on the complexation process. Enthalpy of solution data show that malononitrile is solvated by electron pair donation by the solvents and the crown ether is solvated by donating electron pairs to the solvents. The complex is more solvated than the monomers.

UR - http://www.scopus.com/inward/record.url?scp=21344488257&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=21344488257&partnerID=8YFLogxK

U2 - 10.1007/BF00972717

DO - 10.1007/BF00972717

M3 - Article

AN - SCOPUS:21344488257

SN - 0095-9782

VL - 23

SP - 711

EP - 720

JO - Journal of Solution Chemistry

JF - Journal of Solution Chemistry

IS - 6

ER -

Solvent effects on host-guest complexation

Abstract

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