Solvothermal synthesis of porous conjugated polymer with high surface area for efficient adsorption of organic and biomolecules

Haoyue Zhu; Cuicui Wang; Jun Zhou; Mimi Wan; Ying Wang; Zhigang Zou; Mauricio Terrones

doi:10.1007/s10934-018-0579-2

Solvothermal synthesis of porous conjugated polymer with high surface area for efficient adsorption of organic and biomolecules

Haoyue Zhu, Cuicui Wang, Jun Zhou, Mimi Wan, Ying Wang, Zhigang Zou, Mauricio Terrones

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Aimed to prepare high efficient dye sorbent and control water pollution, herein we utilized solvothermal method to synthesize porous polyimide (PI) polymer with a large surface area using DMSO as solvent. Unlike the solid-state thermal polymerized PI with low surface area of 5 m²g⁻¹, this PI material prepared in DMSO solvent possessed a large surface area of 430 m²g⁻¹, which was beneficial for adsorption of organic dye in waste water, achieving a max MO adsorption of 200 mg g⁻¹ three times higher than that of multiwalled carbon nanotube. The adsorption kinetics of dye molecules on PI was investigated in detail and the R² value of 0.99071 for pseudo-second-order model confirms the adsorption was fitted best with Langmuir isotherm.

Original language	English (US)
Pages (from-to)	1659-1668
Number of pages	10
Journal	Journal of Porous Materials
Volume	25
Issue number	6
DOIs	https://doi.org/10.1007/s10934-018-0579-2
State	Published - Dec 1 2018

All Science Journal Classification (ASJC) codes

General Materials Science
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1007/s10934-018-0579-2

Cite this

@article{044bd170d2204935b528e357bb260e2e,

title = "Solvothermal synthesis of porous conjugated polymer with high surface area for efficient adsorption of organic and biomolecules",

abstract = "Aimed to prepare high efficient dye sorbent and control water pollution, herein we utilized solvothermal method to synthesize porous polyimide (PI) polymer with a large surface area using DMSO as solvent. Unlike the solid-state thermal polymerized PI with low surface area of 5 m2g−1, this PI material prepared in DMSO solvent possessed a large surface area of 430 m2g−1, which was beneficial for adsorption of organic dye in waste water, achieving a max MO adsorption of 200 mg g−1 three times higher than that of multiwalled carbon nanotube. The adsorption kinetics of dye molecules on PI was investigated in detail and the R2 value of 0.99071 for pseudo-second-order model confirms the adsorption was fitted best with Langmuir isotherm.",

author = "Haoyue Zhu and Cuicui Wang and Jun Zhou and Mimi Wan and Ying Wang and Zhigang Zou and Mauricio Terrones",

note = "Funding Information: This work was financially supported by NSFC (21773113), and the authors would like to thank Analysis Center of Nanjing University for the sample characterization and the National Supercomputing Center in Shenzhen for computational facilities. Publisher Copyright: {\textcopyright} 2018, Springer Science+Business Media, LLC, part of Springer Nature.",

year = "2018",

month = dec,

day = "1",

doi = "10.1007/s10934-018-0579-2",

language = "English (US)",

volume = "25",

pages = "1659--1668",

journal = "Journal of Porous Materials",

issn = "1380-2224",

publisher = "Springer Netherlands",

number = "6",

}

TY - JOUR

T1 - Solvothermal synthesis of porous conjugated polymer with high surface area for efficient adsorption of organic and biomolecules

AU - Zhu, Haoyue

AU - Wang, Cuicui

AU - Zhou, Jun

AU - Wan, Mimi

AU - Wang, Ying

AU - Zou, Zhigang

AU - Terrones, Mauricio

N1 - Funding Information: This work was financially supported by NSFC (21773113), and the authors would like to thank Analysis Center of Nanjing University for the sample characterization and the National Supercomputing Center in Shenzhen for computational facilities. Publisher Copyright: © 2018, Springer Science+Business Media, LLC, part of Springer Nature.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - Aimed to prepare high efficient dye sorbent and control water pollution, herein we utilized solvothermal method to synthesize porous polyimide (PI) polymer with a large surface area using DMSO as solvent. Unlike the solid-state thermal polymerized PI with low surface area of 5 m2g−1, this PI material prepared in DMSO solvent possessed a large surface area of 430 m2g−1, which was beneficial for adsorption of organic dye in waste water, achieving a max MO adsorption of 200 mg g−1 three times higher than that of multiwalled carbon nanotube. The adsorption kinetics of dye molecules on PI was investigated in detail and the R2 value of 0.99071 for pseudo-second-order model confirms the adsorption was fitted best with Langmuir isotherm.

AB - Aimed to prepare high efficient dye sorbent and control water pollution, herein we utilized solvothermal method to synthesize porous polyimide (PI) polymer with a large surface area using DMSO as solvent. Unlike the solid-state thermal polymerized PI with low surface area of 5 m2g−1, this PI material prepared in DMSO solvent possessed a large surface area of 430 m2g−1, which was beneficial for adsorption of organic dye in waste water, achieving a max MO adsorption of 200 mg g−1 three times higher than that of multiwalled carbon nanotube. The adsorption kinetics of dye molecules on PI was investigated in detail and the R2 value of 0.99071 for pseudo-second-order model confirms the adsorption was fitted best with Langmuir isotherm.

UR - http://www.scopus.com/inward/record.url?scp=85041912423&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85041912423&partnerID=8YFLogxK

U2 - 10.1007/s10934-018-0579-2

DO - 10.1007/s10934-018-0579-2

M3 - Article

AN - SCOPUS:85041912423

SN - 1380-2224

VL - 25

SP - 1659

EP - 1668

JO - Journal of Porous Materials

JF - Journal of Porous Materials

IS - 6

ER -

Solvothermal synthesis of porous conjugated polymer with high surface area for efficient adsorption of organic and biomolecules

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this