Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior

Dennis Awasabisah; Nan Xu; Krishna P. Sharmah Gautam; Douglas R. Powell; Michael J. Shaw; George B. Richter-Addo

doi:10.1039/c3dt33109a

Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior

Dennis Awasabisah, Nan Xu, Krishna P. Sharmah Gautam, Douglas R. Powell, Michael J. Shaw, George B. Richter-Addo

Division of Mathematics & Natural Sciences (Altoona)

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC₆HF ₄) and (T(p-OMe)PP)Ru(NO)(OC(O)CF₃) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.

Original language	English (US)
Pages (from-to)	8537-8540
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	24
DOIs	https://doi.org/10.1039/c3dt33109a
State	Published - Jun 28 2013

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/c3dt33109a

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abstract = "The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC6HF 4) and (T(p-OMe)PP)Ru(NO)(OC(O)CF3) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.",

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AU - Awasabisah, Dennis

AU - Xu, Nan

AU - Sharmah Gautam, Krishna P.

AU - Powell, Douglas R.

AU - Shaw, Michael J.

AU - Richter-Addo, George B.

PY - 2013/6/28

Y1 - 2013/6/28

N2 - The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC6HF 4) and (T(p-OMe)PP)Ru(NO)(OC(O)CF3) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.

AB - The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC6HF 4) and (T(p-OMe)PP)Ru(NO)(OC(O)CF3) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.

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Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior

Abstract

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