State of water in disulfonated poly(arylene ether sulfone) copolymers and a perfluorosulfonic acid copolymer (nafion) and its effect on physical and electrochemical properties

Yu Seung Kim; Limin Dong; Michael A. Hickner; Thomas E. Glass; Vernon Webb; James E. McGrath

doi:10.1021/ma0301451

State of water in disulfonated poly(arylene ether sulfone) copolymers and a perfluorosulfonic acid copolymer (nafion) and its effect on physical and electrochemical properties

Yu Seung Kim
, Limin Dong
, Michael A. Hickner
, Thomas E. Glass
, Vernon Webb
, James E. McGrath

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

388 Scopus citations

Abstract

Copolymerized sulfonated poly(arylene ether sulfone) copolymers and the standard perfluorinated copolymer, Nafion, were studied. The state of water in the copolymers was quantified by both pressure differential scanning calorimetry (DSC) and ¹H pulse NMR techniques. In addition to DSC and NMR results, methanol permeation and electro-osmotic drag data were considered were considered as additional examples of properties that are directly affected by the state of water.

Original language	English (US)
Pages (from-to)	6281-6285
Number of pages	5
Journal	Macromolecules
Volume	36
Issue number	17
DOIs	https://doi.org/10.1021/ma0301451
State	Published - Aug 26 2003

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma0301451

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title = "State of water in disulfonated poly(arylene ether sulfone) copolymers and a perfluorosulfonic acid copolymer (nafion) and its effect on physical and electrochemical properties",

abstract = "Copolymerized sulfonated poly(arylene ether sulfone) copolymers and the standard perfluorinated copolymer, Nafion, were studied. The state of water in the copolymers was quantified by both pressure differential scanning calorimetry (DSC) and 1H pulse NMR techniques. In addition to DSC and NMR results, methanol permeation and electro-osmotic drag data were considered were considered as additional examples of properties that are directly affected by the state of water.",

author = "Kim, \{Yu Seung\} and Limin Dong and Hickner, \{Michael A.\} and Glass, \{Thomas E.\} and Vernon Webb and McGrath, \{James E.\}",

year = "2003",

month = aug,

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doi = "10.1021/ma0301451",

language = "English (US)",

volume = "36",

pages = "6281--6285",

journal = "Macromolecules",

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publisher = "American Chemical Society",

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T1 - State of water in disulfonated poly(arylene ether sulfone) copolymers and a perfluorosulfonic acid copolymer (nafion) and its effect on physical and electrochemical properties

AU - Kim, Yu Seung

AU - Dong, Limin

AU - Hickner, Michael A.

AU - Glass, Thomas E.

AU - Webb, Vernon

AU - McGrath, James E.

PY - 2003/8/26

Y1 - 2003/8/26

N2 - Copolymerized sulfonated poly(arylene ether sulfone) copolymers and the standard perfluorinated copolymer, Nafion, were studied. The state of water in the copolymers was quantified by both pressure differential scanning calorimetry (DSC) and 1H pulse NMR techniques. In addition to DSC and NMR results, methanol permeation and electro-osmotic drag data were considered were considered as additional examples of properties that are directly affected by the state of water.

AB - Copolymerized sulfonated poly(arylene ether sulfone) copolymers and the standard perfluorinated copolymer, Nafion, were studied. The state of water in the copolymers was quantified by both pressure differential scanning calorimetry (DSC) and 1H pulse NMR techniques. In addition to DSC and NMR results, methanol permeation and electro-osmotic drag data were considered were considered as additional examples of properties that are directly affected by the state of water.

UR - https://www.scopus.com/pages/publications/0042320932

UR - https://www.scopus.com/pages/publications/0042320932#tab=citedBy

U2 - 10.1021/ma0301451

DO - 10.1021/ma0301451

M3 - Article

AN - SCOPUS:0042320932

SN - 0024-9297

VL - 36

SP - 6281

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JO - Macromolecules

JF - Macromolecules

IS - 17

ER -

State of water in disulfonated poly(arylene ether sulfone) copolymers and a perfluorosulfonic acid copolymer (nafion) and its effect on physical and electrochemical properties

Abstract

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