Stereoselective preparation of vinyl sulfones by protodesilylation of allyl silanes

Raymond L. Funk; Joy Umstead-Daggett; Kay M. Brummond

doi:10.1016/S0040-4039(00)60467-7

Stereoselective preparation of vinyl sulfones by protodesilylation of allyl silanes

Raymond L. Funk
, Joy Umstead-Daggett
, Kay M. Brummond

Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Allyl sulfones can be conjugated to furnish vinyl sulfones via allyl silane intermediates. The stereoselectivity observed in the protodesilylation step provides a new method for stereoselective preparation of (E)-di-and trisubstituted vinyl sulfones.

Original language	English (US)
Pages (from-to)	2867-2870
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	18
DOIs	https://doi.org/10.1016/S0040-4039(00)60467-7
State	Published - Apr 30 1993

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)60467-7

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@article{1c999a6cef1a45749550a73f799f6ac3,

title = "Stereoselective preparation of vinyl sulfones by protodesilylation of allyl silanes",

abstract = "Allyl sulfones can be conjugated to furnish vinyl sulfones via allyl silane intermediates. The stereoselectivity observed in the protodesilylation step provides a new method for stereoselective preparation of (E)-di-and trisubstituted vinyl sulfones.",

author = "Funk, \{Raymond L.\} and Joy Umstead-Daggett and Brummond, \{Kay M.\}",

year = "1993",

month = apr,

day = "30",

doi = "10.1016/S0040-4039(00)60467-7",

language = "English (US)",

volume = "34",

pages = "2867--2870",

journal = "Tetrahedron Letters",

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T1 - Stereoselective preparation of vinyl sulfones by protodesilylation of allyl silanes

AU - Funk, Raymond L.

AU - Umstead-Daggett, Joy

AU - Brummond, Kay M.

PY - 1993/4/30

Y1 - 1993/4/30

N2 - Allyl sulfones can be conjugated to furnish vinyl sulfones via allyl silane intermediates. The stereoselectivity observed in the protodesilylation step provides a new method for stereoselective preparation of (E)-di-and trisubstituted vinyl sulfones.

AB - Allyl sulfones can be conjugated to furnish vinyl sulfones via allyl silane intermediates. The stereoselectivity observed in the protodesilylation step provides a new method for stereoselective preparation of (E)-di-and trisubstituted vinyl sulfones.

UR - https://www.scopus.com/pages/publications/0027212341

UR - https://www.scopus.com/pages/publications/0027212341#tab=citedBy

U2 - 10.1016/S0040-4039(00)60467-7

DO - 10.1016/S0040-4039(00)60467-7

M3 - Article

AN - SCOPUS:0027212341

SN - 0040-4039

VL - 34

SP - 2867

EP - 2870

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 18

ER -

Stereoselective preparation of vinyl sulfones by protodesilylation of allyl silanes

Abstract

All Science Journal Classification (ASJC) codes

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