Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode

Jin Xie, Lei Liao, Yongji Gong, Yanbin Li, Feifei Shi, Allen Pei, Jie Sun, Rufan Zhang, Biao Kong, Ram Subbaraman, Jake Christensen, Yi Cui

Research output: Contribution to journalArticlepeer-review

238 Scopus citations


Defects are important features in two-dimensional (2D) materials that have a strong influence on their chemical and physical properties. Through the enhanced chemical reactivity at defect sites (point defects, line defects, etc.). One can selectively functionalize 2D materials via chemical reactions and thereby tune their physical properties. We demonstrate the selective atomic layer deposition of LiF on defect sites of h-BN prepared by chemical vapor deposition. The LiF deposits primarily on the line and point defects of h-BN, thereby creating seams that hold the h-BN crystallites together. The chemically and mechanically stable hybrid LiF/h-BN film successfully suppresses lithium dendrite formation during both the initial electrochemical deposition onto a copper foil and the subsequent cycling. The protected lithium electrodes exhibit good cycling behavior with more than 300 cycles at relatively high coulombic efficiency (>in an additive-free carbonate electrolyte.

Original languageEnglish (US)
Article numbereaao3170
JournalScience Advances
Issue number11
StatePublished - Nov 2017

All Science Journal Classification (ASJC) codes

  • General


Dive into the research topics of 'Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode'. Together they form a unique fingerprint.

Cite this