Structured electrochemical materials fabricated from directed self-assembly of block copolymers and advanced lithography

L. Zhang; C. Cao; A. Yakimov; C. G. Arges

doi:10.1149/08008.0971ecst

Structured electrochemical materials fabricated from directed self-assembly of block copolymers and advanced lithography

L. Zhang
, C. Cao
, A. Yakimov
, C. G. Arges

Chemical Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Nanolithography has propelled faster computer chips and even smaller electronic devices, but this patterning technique has not seen widespread adoption for making structured electrochemical materials. A prominent nanopatteming platform championed by numerous semiconductor manufactures is block copolymer lithography. Block copolymers spontaneously self-assemble at the molecular level and they can be directed into long-range ordered, perfect structures via directed self-assembly. Hence, they are attractive candidates for systematic study relating nanostructure to charge-transfer kinetics and transport phenomena. This report highlights the use of block copolymers to study ionic conductivity in microphase separated polymer electrolyte films and for patterning bulk ion-exchange membranes and glassy carbon substrates.

Original language	English (US)
Title of host publication	ECS Transactions
Editors	D. J. Jones, F. Buechi, K. E. Swider-Lyons, P. N. Pintauro, H. Uchida, T. J. Schmidt, B. S. Pivovar, H. A. Gasteiger, A. Z. Weber, P. A. Shirvanian, J. M. Fenton, T. F. Fuller, K. Shinohara, K. A. Perry, P. Strasser, C. Coutanceau, S. Mitsushima, R. A. Mantz, S. Narayan, V. Ramani, K. E. Ayers, Y.-T. Kim, H. Xu
Publisher	Electrochemical Society Inc.
Pages	971-978
Number of pages	8
Edition	8
ISBN (Print)	9781623324773
DOIs	https://doi.org/10.1149/08008.0971ecst
State	Published - 2017
Event	Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting - National Harbor, United States Duration: Oct 1 2017 → Oct 5 2017

Publication series

Name	ECS Transactions
Number	8
Volume	80
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting
Country/Territory	United States
City	National Harbor
Period	10/1/17 → 10/5/17

All Science Journal Classification (ASJC) codes

General Engineering

Access to Document

10.1149/08008.0971ecst

Cite this

Zhang, L., Cao, C., Yakimov, A., & Arges, C. G. (2017). Structured electrochemical materials fabricated from directed self-assembly of block copolymers and advanced lithography. In D. J. Jones, F. Buechi, K. E. Swider-Lyons, P. N. Pintauro, H. Uchida, T. J. Schmidt, B. S. Pivovar, H. A. Gasteiger, A. Z. Weber, P. A. Shirvanian, J. M. Fenton, T. F. Fuller, K. Shinohara, K. A. Perry, P. Strasser, C. Coutanceau, S. Mitsushima, R. A. Mantz, S. Narayan, V. Ramani, K. E. Ayers, Y.-T. Kim, ... H. Xu (Eds.), ECS Transactions (8 ed., pp. 971-978). (ECS Transactions; Vol. 80, No. 8). Electrochemical Society Inc.. https://doi.org/10.1149/08008.0971ecst

Zhang, L. ; Cao, C. ; Yakimov, A. et al. / Structured electrochemical materials fabricated from directed self-assembly of block copolymers and advanced lithography. ECS Transactions. editor / D. J. Jones ; F. Buechi ; K. E. Swider-Lyons ; P. N. Pintauro ; H. Uchida ; T. J. Schmidt ; B. S. Pivovar ; H. A. Gasteiger ; A. Z. Weber ; P. A. Shirvanian ; J. M. Fenton ; T. F. Fuller ; K. Shinohara ; K. A. Perry ; P. Strasser ; C. Coutanceau ; S. Mitsushima ; R. A. Mantz ; S. Narayan ; V. Ramani ; K. E. Ayers ; Y.-T. Kim ; H. Xu. 8. ed. Electrochemical Society Inc., 2017. pp. 971-978 (ECS Transactions; 8).

@inproceedings{17afd15cf7134ebc877da9ac109bfa2b,

title = "Structured electrochemical materials fabricated from directed self-assembly of block copolymers and advanced lithography",

abstract = "Nanolithography has propelled faster computer chips and even smaller electronic devices, but this patterning technique has not seen widespread adoption for making structured electrochemical materials. A prominent nanopatteming platform championed by numerous semiconductor manufactures is block copolymer lithography. Block copolymers spontaneously self-assemble at the molecular level and they can be directed into long-range ordered, perfect structures via directed self-assembly. Hence, they are attractive candidates for systematic study relating nanostructure to charge-transfer kinetics and transport phenomena. This report highlights the use of block copolymers to study ionic conductivity in microphase separated polymer electrolyte films and for patterning bulk ion-exchange membranes and glassy carbon substrates.",

author = "L. Zhang and C. Cao and A. Yakimov and Arges, \{C. G.\}",

note = "Funding Information: We gratefully acknowledge funding from the National Science Foundation (Award \# NSF-CBET-1703307). We also acknowledge the generous donation of PFAEM material supplied from Dr. Andrew Park and Dr. Bryan Pivovar from the National Renewable Energy Laboratory and the Shared Instrumentation Facility at Louisiana State University for access to the scanning electron microscope. Publisher Copyright: {\textcopyright} The Electrochemical Society.; Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting ; Conference date: 01-10-2017 Through 05-10-2017",

year = "2017",

doi = "10.1149/08008.0971ecst",

language = "English (US)",

isbn = "9781623324773",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "8",

pages = "971--978",

editor = "Jones, \{D. J.\} and F. Buechi and Swider-Lyons, \{K. E.\} and Pintauro, \{P. N.\} and H. Uchida and Schmidt, \{T. J.\} and Pivovar, \{B. S.\} and Gasteiger, \{H. A.\} and Weber, \{A. Z.\} and Shirvanian, \{P. A.\} and Fenton, \{J. M.\} and Fuller, \{T. F.\} and K. Shinohara and Perry, \{K. A.\} and P. Strasser and C. Coutanceau and S. Mitsushima and Mantz, \{R. A.\} and S. Narayan and V. Ramani and Ayers, \{K. E.\} and Y.-T. Kim and H. Xu",

booktitle = "ECS Transactions",

edition = "8",

}

Zhang, L, Cao, C, Yakimov, A & Arges, CG 2017, Structured electrochemical materials fabricated from directed self-assembly of block copolymers and advanced lithography. in DJ Jones, F Buechi, KE Swider-Lyons, PN Pintauro, H Uchida, TJ Schmidt, BS Pivovar, HA Gasteiger, AZ Weber, PA Shirvanian, JM Fenton, TF Fuller, K Shinohara, KA Perry, P Strasser, C Coutanceau, S Mitsushima, RA Mantz, S Narayan, V Ramani, KE Ayers, Y-T Kim & H Xu (eds), ECS Transactions. 8 edn, ECS Transactions, no. 8, vol. 80, Electrochemical Society Inc., pp. 971-978, Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting, National Harbor, United States, 10/1/17. https://doi.org/10.1149/08008.0971ecst

Structured electrochemical materials fabricated from directed self-assembly of block copolymers and advanced lithography. / Zhang, L.; Cao, C.; Yakimov, A. et al.
ECS Transactions. ed. / D. J. Jones; F. Buechi; K. E. Swider-Lyons; P. N. Pintauro; H. Uchida; T. J. Schmidt; B. S. Pivovar; H. A. Gasteiger; A. Z. Weber; P. A. Shirvanian; J. M. Fenton; T. F. Fuller; K. Shinohara; K. A. Perry; P. Strasser; C. Coutanceau; S. Mitsushima; R. A. Mantz; S. Narayan; V. Ramani; K. E. Ayers; Y.-T. Kim; H. Xu. 8. ed. Electrochemical Society Inc., 2017. p. 971-978 (ECS Transactions; Vol. 80, No. 8).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

TY - GEN

T1 - Structured electrochemical materials fabricated from directed self-assembly of block copolymers and advanced lithography

AU - Zhang, L.

AU - Cao, C.

AU - Yakimov, A.

AU - Arges, C. G.

N1 - Funding Information: We gratefully acknowledge funding from the National Science Foundation (Award # NSF-CBET-1703307). We also acknowledge the generous donation of PFAEM material supplied from Dr. Andrew Park and Dr. Bryan Pivovar from the National Renewable Energy Laboratory and the Shared Instrumentation Facility at Louisiana State University for access to the scanning electron microscope. Publisher Copyright: © The Electrochemical Society.

PY - 2017

Y1 - 2017

N2 - Nanolithography has propelled faster computer chips and even smaller electronic devices, but this patterning technique has not seen widespread adoption for making structured electrochemical materials. A prominent nanopatteming platform championed by numerous semiconductor manufactures is block copolymer lithography. Block copolymers spontaneously self-assemble at the molecular level and they can be directed into long-range ordered, perfect structures via directed self-assembly. Hence, they are attractive candidates for systematic study relating nanostructure to charge-transfer kinetics and transport phenomena. This report highlights the use of block copolymers to study ionic conductivity in microphase separated polymer electrolyte films and for patterning bulk ion-exchange membranes and glassy carbon substrates.

AB - Nanolithography has propelled faster computer chips and even smaller electronic devices, but this patterning technique has not seen widespread adoption for making structured electrochemical materials. A prominent nanopatteming platform championed by numerous semiconductor manufactures is block copolymer lithography. Block copolymers spontaneously self-assemble at the molecular level and they can be directed into long-range ordered, perfect structures via directed self-assembly. Hence, they are attractive candidates for systematic study relating nanostructure to charge-transfer kinetics and transport phenomena. This report highlights the use of block copolymers to study ionic conductivity in microphase separated polymer electrolyte films and for patterning bulk ion-exchange membranes and glassy carbon substrates.

UR - https://www.scopus.com/pages/publications/85050012000

UR - https://www.scopus.com/pages/publications/85050012000#tab=citedBy

U2 - 10.1149/08008.0971ecst

DO - 10.1149/08008.0971ecst

M3 - Conference contribution

AN - SCOPUS:85050012000

SN - 9781623324773

T3 - ECS Transactions

SP - 971

EP - 978

BT - ECS Transactions

A2 - Jones, D. J.

A2 - Buechi, F.

A2 - Swider-Lyons, K. E.

A2 - Pintauro, P. N.

A2 - Uchida, H.

A2 - Schmidt, T. J.

A2 - Pivovar, B. S.

A2 - Gasteiger, H. A.

A2 - Weber, A. Z.

A2 - Shirvanian, P. A.

A2 - Fenton, J. M.

A2 - Fuller, T. F.

A2 - Shinohara, K.

A2 - Perry, K. A.

A2 - Strasser, P.

A2 - Coutanceau, C.

A2 - Mitsushima, S.

A2 - Mantz, R. A.

A2 - Narayan, S.

A2 - Ramani, V.

A2 - Ayers, K. E.

A2 - Kim, Y.-T.

A2 - Xu, H.

PB - Electrochemical Society Inc.

T2 - Symposium on Polymer Electrolyte Fuel Cells 17, PEFC 2017 - 232nd ECS Meeting

Y2 - 1 October 2017 through 5 October 2017

ER -

Zhang L, Cao C, Yakimov A, Arges CG. Structured electrochemical materials fabricated from directed self-assembly of block copolymers and advanced lithography. In Jones DJ, Buechi F, Swider-Lyons KE, Pintauro PN, Uchida H, Schmidt TJ, Pivovar BS, Gasteiger HA, Weber AZ, Shirvanian PA, Fenton JM, Fuller TF, Shinohara K, Perry KA, Strasser P, Coutanceau C, Mitsushima S, Mantz RA, Narayan S, Ramani V, Ayers KE, Kim YT, Xu H, editors, ECS Transactions. 8 ed. Electrochemical Society Inc. 2017. p. 971-978. (ECS Transactions; 8). doi: 10.1149/08008.0971ecst

Structured electrochemical materials fabricated from directed self-assembly of block copolymers and advanced lithography

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