Study of the products of the reactions of N2(A3Σu+): The effect of vibrational energy in N2(A)

Michael F. Golde; Alfred M. Moyle

doi:10.1016/0009-2614(85)85247-7

Study of the products of the reactions of N₂(A³Σ_u⁺): The effect of vibrational energy in N₂(A)

Michael F. Golde
, Alfred M. Moyle

Meteorology and Atmospheric Science

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

The reactions of electronically excited N₂(A³Σ_u⁺) molecules with selected small molecules have been studied in a discharge-flow system. A method is described for probing, with high sensitivity, the dependence of total quenching rate constants and reaction pathways on vibrational energy in the N₂(A) state. Highly characteristic behavior is observed in the reactions with NH₃, CH₃OH, NO and O₂.

Original language	English (US)
Pages (from-to)	375-380
Number of pages	6
Journal	Chemical Physics Letters
Volume	117
Issue number	4
DOIs	https://doi.org/10.1016/0009-2614(85)85247-7
State	Published - Jun 21 1985

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(85)85247-7

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title = "Study of the products of the reactions of N2(A3Σu+): The effect of vibrational energy in N2(A)",

abstract = "The reactions of electronically excited N2(A3Σu+) molecules with selected small molecules have been studied in a discharge-flow system. A method is described for probing, with high sensitivity, the dependence of total quenching rate constants and reaction pathways on vibrational energy in the N2(A) state. Highly characteristic behavior is observed in the reactions with NH3, CH3OH, NO and O2.",

author = "Golde, \{Michael F.\} and Moyle, \{Alfred M.\}",

note = "Funding Information: We gratefully a\textasciitilde{}nowledge the Air Force Office of Scientific Research, Grant No. 83-0188, for support of this research..",

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T1 - Study of the products of the reactions of N2(A3Σu+)

T2 - The effect of vibrational energy in N2(A)

AU - Golde, Michael F.

AU - Moyle, Alfred M.

N1 - Funding Information: We gratefully a~nowledge the Air Force Office of Scientific Research, Grant No. 83-0188, for support of this research..

PY - 1985/6/21

Y1 - 1985/6/21

N2 - The reactions of electronically excited N2(A3Σu+) molecules with selected small molecules have been studied in a discharge-flow system. A method is described for probing, with high sensitivity, the dependence of total quenching rate constants and reaction pathways on vibrational energy in the N2(A) state. Highly characteristic behavior is observed in the reactions with NH3, CH3OH, NO and O2.

AB - The reactions of electronically excited N2(A3Σu+) molecules with selected small molecules have been studied in a discharge-flow system. A method is described for probing, with high sensitivity, the dependence of total quenching rate constants and reaction pathways on vibrational energy in the N2(A) state. Highly characteristic behavior is observed in the reactions with NH3, CH3OH, NO and O2.

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U2 - 10.1016/0009-2614(85)85247-7

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AN - SCOPUS:4243583199

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JO - Chemical Physics Letters

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IS - 4

ER -

Study of the products of the reactions of N₂(A³Σ_u⁺): The effect of vibrational energy in N₂(A)

Abstract

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