Abstract
The reaction between silicon tetrachloride and catechol in acetonitrile at 0° results in the formation of o-phenylenedioxydichlorosilane (I) and bis(o-phenylenedioxy)silane (III). The former compound exists both as a monomer-dimer mixture (I and II) and as the pure dimer (II). 2,2’-Biphenylenedioxy-bis(methoxy)silane (V) was also prepared and its facile conversion to bis(2,2’-biphenylenedioxy)silane (VI) was observed.
Original language | English (US) |
---|---|
Pages (from-to) | 97-104 |
Number of pages | 8 |
Journal | Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry |
Volume | 2 |
Issue number | 2 |
DOIs | |
State | Published - Jan 1 1972 |
All Science Journal Classification (ASJC) codes
- Inorganic Chemistry