Synchrotron texture analysis of thick BiFeO 3-PbTiO 3 layers synthesised by tape casting using Aurivillius and non-Aurivillius templates

Meghdad Palizdar; Tim P. Comyn; Stephen F. Poterala; Gary L. Messing; Ender Suvaci; Annette P. Kleppe; Andrew J. Jephcoat; Andrew J. Bell

doi:10.1109/ISAF.2012.6297816

Synchrotron texture analysis of thick BiFeO ₃-PbTiO ₃ layers synthesised by tape casting using Aurivillius and non-Aurivillius templates

Meghdad Palizdar, Tim P. Comyn, Stephen F. Poterala, Gary L. Messing, Ender Suvaci, Annette P. Kleppe, Andrew J. Jephcoat, Andrew J. Bell

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

2 Scopus citations

Abstract

The solid solution between bismuth ferrite and lead titanate (xBiFeO ₃-(1-x)PbTiO ₃ or BFPT) possesses a morphotropic phase boundary (MPB) between the rhombohedral and tetragonal forms at x=0.7. It is of interest to investigate the influence of field-driven rhombohedral-tetragonal phase transitions across the MPB, to determine whether correctly oriented BFPT can provide both giant piezoelectric properties and significant magnetoelectric coupling. Here, we used the reactive templated grain growth (RTGG) technique to prepare crystallographically textured 0.6BiFeO ₃-0.4PbTiO ₃ (60:40 BFPT) ceramics. Both Aurivillius structure templates (Bi ₄Ti ₃O ₁₂ and PbBi ₄Ti ₄O ₁₅) and perovskite templates (BaTiO ₃ and SrTiO ₃) were used to prepare textured 60:40BFPT. Synchrotron radiation experiments were used to determine the degree of texture. A current data suggests that only BaTiO ₃ templates survive the sintering process, and other candidate template materials reacted with the 60:40BFPT matrix at high temperature. In the case of SrTiO ₃, this reaction results in a low Curie temperature (T _c = 350 °C) due to the substitution of Sr ²⁺. Aurivillius templates resulted in high Curie temperatures (610 °C) and may be chemically suitable if they could be stabilized during the sintering process. However, the resulting ceramics show low remanent polarization (P _r = 3 μc/cm ²), while SrTiO ₃ and BaTiO ₃ templated ceramics show higher remanent polarizations of 36 and 30 μc/cm ², respectively. Because of their high chemical stability in this system, BaTiO ₃ templates appear to be the best candidate for fabricating textured BFPT by the TGG method, displaying a high degree of crystallographic texture.

Original language	English (US)
Title of host publication	Proc. of 2012 21st IEEE International Symposium on Applications of Ferroelectrics Held Jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE, ISAF/ECAPD/PFM 2012
DOIs	https://doi.org/10.1109/ISAF.2012.6297816
State	Published - 2012
Event	2012 21st IEEE Int. Symp. on Applications of Ferroelectrics Held with 11th IEEE European Conf. on Applications of Polar Dielectrics and 4th IEEE Int. Symp on Piezoresponse Force Microscopy and Nanoscale Phenomena in Polar Materials, ISAF/ECAPD/PFM - Aveiro, Portugal Duration: Jul 9 2012 → Jul 13 2012

Publication series

Name	Proceedings of 2012 21st IEEE Int. Symp. on Applications of Ferroelectrics held jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE PFM, ISAF/ECAPD/PFM 2012

Other

Other	2012 21st IEEE Int. Symp. on Applications of Ferroelectrics Held with 11th IEEE European Conf. on Applications of Polar Dielectrics and 4th IEEE Int. Symp on Piezoresponse Force Microscopy and Nanoscale Phenomena in Polar Materials, ISAF/ECAPD/PFM
Country/Territory	Portugal
City	Aveiro
Period	7/9/12 → 7/13/12

All Science Journal Classification (ASJC) codes

Electrical and Electronic Engineering

Access to Document

10.1109/ISAF.2012.6297816

Cite this

Palizdar, M., Comyn, T. P., Poterala, S. F., Messing, G. L., Suvaci, E., Kleppe, A. P., Jephcoat, A. J., & Bell, A. J. (2012). Synchrotron texture analysis of thick BiFeO ₃-PbTiO ₃ layers synthesised by tape casting using Aurivillius and non-Aurivillius templates. In Proc. of 2012 21st IEEE International Symposium on Applications of Ferroelectrics Held Jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE, ISAF/ECAPD/PFM 2012 Article 6297816 (Proceedings of 2012 21st IEEE Int. Symp. on Applications of Ferroelectrics held jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE PFM, ISAF/ECAPD/PFM 2012). https://doi.org/10.1109/ISAF.2012.6297816

Palizdar, Meghdad ; Comyn, Tim P. ; Poterala, Stephen F. et al. / Synchrotron texture analysis of thick BiFeO ₃-PbTiO ₃ layers synthesised by tape casting using Aurivillius and non-Aurivillius templates. Proc. of 2012 21st IEEE International Symposium on Applications of Ferroelectrics Held Jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE, ISAF/ECAPD/PFM 2012. 2012. (Proceedings of 2012 21st IEEE Int. Symp. on Applications of Ferroelectrics held jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE PFM, ISAF/ECAPD/PFM 2012).

@inproceedings{bd662b52757245268b97d99061e8bd27,

title = "Synchrotron texture analysis of thick BiFeO 3-PbTiO 3 layers synthesised by tape casting using Aurivillius and non-Aurivillius templates",

abstract = "The solid solution between bismuth ferrite and lead titanate (xBiFeO 3-(1-x)PbTiO 3 or BFPT) possesses a morphotropic phase boundary (MPB) between the rhombohedral and tetragonal forms at x=0.7. It is of interest to investigate the influence of field-driven rhombohedral-tetragonal phase transitions across the MPB, to determine whether correctly oriented BFPT can provide both giant piezoelectric properties and significant magnetoelectric coupling. Here, we used the reactive templated grain growth (RTGG) technique to prepare crystallographically textured 0.6BiFeO 3-0.4PbTiO 3 (60:40 BFPT) ceramics. Both Aurivillius structure templates (Bi 4Ti 3O 12 and PbBi 4Ti 4O 15) and perovskite templates (BaTiO 3 and SrTiO 3) were used to prepare textured 60:40BFPT. Synchrotron radiation experiments were used to determine the degree of texture. A current data suggests that only BaTiO 3 templates survive the sintering process, and other candidate template materials reacted with the 60:40BFPT matrix at high temperature. In the case of SrTiO 3, this reaction results in a low Curie temperature (T c = 350 °C) due to the substitution of Sr 2+. Aurivillius templates resulted in high Curie temperatures (610 °C) and may be chemically suitable if they could be stabilized during the sintering process. However, the resulting ceramics show low remanent polarization (P r = 3 μc/cm 2), while SrTiO 3 and BaTiO 3 templated ceramics show higher remanent polarizations of 36 and 30 μc/cm 2, respectively. Because of their high chemical stability in this system, BaTiO 3 templates appear to be the best candidate for fabricating textured BFPT by the TGG method, displaying a high degree of crystallographic texture.",

author = "Meghdad Palizdar and Comyn, {Tim P.} and Poterala, {Stephen F.} and Messing, {Gary L.} and Ender Suvaci and Kleppe, {Annette P.} and Jephcoat, {Andrew J.} and Bell, {Andrew J.}",

year = "2012",

doi = "10.1109/ISAF.2012.6297816",

language = "English (US)",

isbn = "9781467326681",

series = "Proceedings of 2012 21st IEEE Int. Symp. on Applications of Ferroelectrics held jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE PFM, ISAF/ECAPD/PFM 2012",

booktitle = "Proc. of 2012 21st IEEE International Symposium on Applications of Ferroelectrics Held Jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE, ISAF/ECAPD/PFM 2012",

note = "2012 21st IEEE Int. Symp. on Applications of Ferroelectrics Held with 11th IEEE European Conf. on Applications of Polar Dielectrics and 4th IEEE Int. Symp on Piezoresponse Force Microscopy and Nanoscale Phenomena in Polar Materials, ISAF/ECAPD/PFM ; Conference date: 09-07-2012 Through 13-07-2012",

}

Palizdar, M, Comyn, TP, Poterala, SF, Messing, GL, Suvaci, E, Kleppe, AP, Jephcoat, AJ & Bell, AJ 2012, Synchrotron texture analysis of thick BiFeO ₃-PbTiO ₃ layers synthesised by tape casting using Aurivillius and non-Aurivillius templates. in Proc. of 2012 21st IEEE International Symposium on Applications of Ferroelectrics Held Jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE, ISAF/ECAPD/PFM 2012., 6297816, Proceedings of 2012 21st IEEE Int. Symp. on Applications of Ferroelectrics held jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE PFM, ISAF/ECAPD/PFM 2012, 2012 21st IEEE Int. Symp. on Applications of Ferroelectrics Held with 11th IEEE European Conf. on Applications of Polar Dielectrics and 4th IEEE Int. Symp on Piezoresponse Force Microscopy and Nanoscale Phenomena in Polar Materials, ISAF/ECAPD/PFM, Aveiro, Portugal, 7/9/12. https://doi.org/10.1109/ISAF.2012.6297816

Synchrotron texture analysis of thick BiFeO ₃-PbTiO ₃ layers synthesised by tape casting using Aurivillius and non-Aurivillius templates. / Palizdar, Meghdad; Comyn, Tim P.; Poterala, Stephen F. et al.
Proc. of 2012 21st IEEE International Symposium on Applications of Ferroelectrics Held Jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE, ISAF/ECAPD/PFM 2012. 2012. 6297816 (Proceedings of 2012 21st IEEE Int. Symp. on Applications of Ferroelectrics held jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE PFM, ISAF/ECAPD/PFM 2012).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

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T1 - Synchrotron texture analysis of thick BiFeO 3-PbTiO 3 layers synthesised by tape casting using Aurivillius and non-Aurivillius templates

AU - Palizdar, Meghdad

AU - Comyn, Tim P.

AU - Poterala, Stephen F.

AU - Messing, Gary L.

AU - Suvaci, Ender

AU - Kleppe, Annette P.

AU - Jephcoat, Andrew J.

AU - Bell, Andrew J.

PY - 2012

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N2 - The solid solution between bismuth ferrite and lead titanate (xBiFeO 3-(1-x)PbTiO 3 or BFPT) possesses a morphotropic phase boundary (MPB) between the rhombohedral and tetragonal forms at x=0.7. It is of interest to investigate the influence of field-driven rhombohedral-tetragonal phase transitions across the MPB, to determine whether correctly oriented BFPT can provide both giant piezoelectric properties and significant magnetoelectric coupling. Here, we used the reactive templated grain growth (RTGG) technique to prepare crystallographically textured 0.6BiFeO 3-0.4PbTiO 3 (60:40 BFPT) ceramics. Both Aurivillius structure templates (Bi 4Ti 3O 12 and PbBi 4Ti 4O 15) and perovskite templates (BaTiO 3 and SrTiO 3) were used to prepare textured 60:40BFPT. Synchrotron radiation experiments were used to determine the degree of texture. A current data suggests that only BaTiO 3 templates survive the sintering process, and other candidate template materials reacted with the 60:40BFPT matrix at high temperature. In the case of SrTiO 3, this reaction results in a low Curie temperature (T c = 350 °C) due to the substitution of Sr 2+. Aurivillius templates resulted in high Curie temperatures (610 °C) and may be chemically suitable if they could be stabilized during the sintering process. However, the resulting ceramics show low remanent polarization (P r = 3 μc/cm 2), while SrTiO 3 and BaTiO 3 templated ceramics show higher remanent polarizations of 36 and 30 μc/cm 2, respectively. Because of their high chemical stability in this system, BaTiO 3 templates appear to be the best candidate for fabricating textured BFPT by the TGG method, displaying a high degree of crystallographic texture.

AB - The solid solution between bismuth ferrite and lead titanate (xBiFeO 3-(1-x)PbTiO 3 or BFPT) possesses a morphotropic phase boundary (MPB) between the rhombohedral and tetragonal forms at x=0.7. It is of interest to investigate the influence of field-driven rhombohedral-tetragonal phase transitions across the MPB, to determine whether correctly oriented BFPT can provide both giant piezoelectric properties and significant magnetoelectric coupling. Here, we used the reactive templated grain growth (RTGG) technique to prepare crystallographically textured 0.6BiFeO 3-0.4PbTiO 3 (60:40 BFPT) ceramics. Both Aurivillius structure templates (Bi 4Ti 3O 12 and PbBi 4Ti 4O 15) and perovskite templates (BaTiO 3 and SrTiO 3) were used to prepare textured 60:40BFPT. Synchrotron radiation experiments were used to determine the degree of texture. A current data suggests that only BaTiO 3 templates survive the sintering process, and other candidate template materials reacted with the 60:40BFPT matrix at high temperature. In the case of SrTiO 3, this reaction results in a low Curie temperature (T c = 350 °C) due to the substitution of Sr 2+. Aurivillius templates resulted in high Curie temperatures (610 °C) and may be chemically suitable if they could be stabilized during the sintering process. However, the resulting ceramics show low remanent polarization (P r = 3 μc/cm 2), while SrTiO 3 and BaTiO 3 templated ceramics show higher remanent polarizations of 36 and 30 μc/cm 2, respectively. Because of their high chemical stability in this system, BaTiO 3 templates appear to be the best candidate for fabricating textured BFPT by the TGG method, displaying a high degree of crystallographic texture.

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BT - Proc. of 2012 21st IEEE International Symposium on Applications of Ferroelectrics Held Jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE, ISAF/ECAPD/PFM 2012

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Palizdar M, Comyn TP, Poterala SF, Messing GL, Suvaci E, Kleppe AP et al. Synchrotron texture analysis of thick BiFeO ₃-PbTiO ₃ layers synthesised by tape casting using Aurivillius and non-Aurivillius templates. In Proc. of 2012 21st IEEE International Symposium on Applications of Ferroelectrics Held Jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE, ISAF/ECAPD/PFM 2012. 2012. 6297816. (Proceedings of 2012 21st IEEE Int. Symp. on Applications of Ferroelectrics held jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE PFM, ISAF/ECAPD/PFM 2012). doi: 10.1109/ISAF.2012.6297816