Synthesis and characterization of a spin crossover iron(ii)-iron(iii) mixed valence supramolecular pseudo-dimer exhibiting chiral recognition, hydrogen bonding, and π-π Interactions

Cynthia T. Brewer; Greg Brewer; Ray J. Butcher; Everett E. Carpenter; Ann M. Schmiedekamp; Carol Viragh

doi:10.1039/b613282k

Synthesis and characterization of a spin crossover iron(ii)-iron(iii) mixed valence supramolecular pseudo-dimer exhibiting chiral recognition, hydrogen bonding, and π-π Interactions

Cynthia T. Brewer, Greg Brewer, Ray J. Butcher, Everett E. Carpenter, Ann M. Schmiedekamp, Carol Viragh

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Reaction of iron(ii) and the 3: 1 Schiff base condensate of 5-methylpyrazole-3-carboxaldehyde and tris(2-aminoethyl)amine in air gives a pseudo-dimer complex with a triple helix structure made of Δ-Δ and Λ-Λ pairings of spin crossover iron(ii) and low spin iron(iii) cations that are held together by three π-π and hydrogen bonding interactions.

Original language	English (US)
Pages (from-to)	295-298
Number of pages	4
Journal	Dalton Transactions
Issue number	3
DOIs	https://doi.org/10.1039/b613282k
State	Published - 2007

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/b613282k

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title = "Synthesis and characterization of a spin crossover iron(ii)-iron(iii) mixed valence supramolecular pseudo-dimer exhibiting chiral recognition, hydrogen bonding, and π-π Interactions",

abstract = "Reaction of iron(ii) and the 3: 1 Schiff base condensate of 5-methylpyrazole-3-carboxaldehyde and tris(2-aminoethyl)amine in air gives a pseudo-dimer complex with a triple helix structure made of Δ-Δ and Λ-Λ pairings of spin crossover iron(ii) and low spin iron(iii) cations that are held together by three π-π and hydrogen bonding interactions.",

author = "Brewer, {Cynthia T.} and Greg Brewer and Butcher, {Ray J.} and Carpenter, {Everett E.} and Schmiedekamp, {Ann M.} and Carol Viragh",

year = "2007",

doi = "10.1039/b613282k",

language = "English (US)",

pages = "295--298",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T1 - Synthesis and characterization of a spin crossover iron(ii)-iron(iii) mixed valence supramolecular pseudo-dimer exhibiting chiral recognition, hydrogen bonding, and π-π Interactions

AU - Brewer, Cynthia T.

AU - Brewer, Greg

AU - Butcher, Ray J.

AU - Carpenter, Everett E.

AU - Schmiedekamp, Ann M.

AU - Viragh, Carol

PY - 2007

Y1 - 2007

N2 - Reaction of iron(ii) and the 3: 1 Schiff base condensate of 5-methylpyrazole-3-carboxaldehyde and tris(2-aminoethyl)amine in air gives a pseudo-dimer complex with a triple helix structure made of Δ-Δ and Λ-Λ pairings of spin crossover iron(ii) and low spin iron(iii) cations that are held together by three π-π and hydrogen bonding interactions.

AB - Reaction of iron(ii) and the 3: 1 Schiff base condensate of 5-methylpyrazole-3-carboxaldehyde and tris(2-aminoethyl)amine in air gives a pseudo-dimer complex with a triple helix structure made of Δ-Δ and Λ-Λ pairings of spin crossover iron(ii) and low spin iron(iii) cations that are held together by three π-π and hydrogen bonding interactions.

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 3

ER -

Synthesis and characterization of a spin crossover iron(ii)-iron(iii) mixed valence supramolecular pseudo-dimer exhibiting chiral recognition, hydrogen bonding, and π-π Interactions

Abstract

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