TY - JOUR
T1 - Synthesis and characterization of copper and nickel complexes of LIX63 oxime
AU - Keeney, M. E.
AU - Osseo-Asare, K.
N1 - Funding Information:
Acknowledgements-Thirse searchw ass upportedb y the National Science Foundation under Grant No. CPE8 110756M. .E.K. acknowledgefse llowships upport by the Mining and Mineral ResourcesR esearchI nsti-tute, The PennsylvaniaS tateUniversity.
Copyright:
Copyright 2014 Elsevier B.V., All rights reserved.
PY - 1984
Y1 - 1984
N2 - Several complexes of 5,8-diethyl-7-hydroxy-6-dodecanone oxime [H2L] with Cu(II) and Ni(II) have been synthesized and characterized by means of a number of techniques including elemental analysis, IR spectra, magnetic susceptibility measurements, electronic absorption spectra, NMR spectra, and mass spectra. The results indicate that Cu(II) and Ni(II) generally form analogous, isomorphous complexes, although no bis-[H2L] complex with Cu(II) has been isolated. [Cu(L)]n and [Ni(L)]n are oligomeric complexes with pseudo-octahedral geometry. [Ni(HL)2] is cis-square-planar (C2ν) with bifurcated hydrogen bridges. [Ni(H2L)3SO4] and [Cu(H2L)3SO4] have octahedral symmetry in which the sulphate is coordinated as a unidentate ligand and the oxime is functioning as a neutral ligand.
AB - Several complexes of 5,8-diethyl-7-hydroxy-6-dodecanone oxime [H2L] with Cu(II) and Ni(II) have been synthesized and characterized by means of a number of techniques including elemental analysis, IR spectra, magnetic susceptibility measurements, electronic absorption spectra, NMR spectra, and mass spectra. The results indicate that Cu(II) and Ni(II) generally form analogous, isomorphous complexes, although no bis-[H2L] complex with Cu(II) has been isolated. [Cu(L)]n and [Ni(L)]n are oligomeric complexes with pseudo-octahedral geometry. [Ni(HL)2] is cis-square-planar (C2ν) with bifurcated hydrogen bridges. [Ni(H2L)3SO4] and [Cu(H2L)3SO4] have octahedral symmetry in which the sulphate is coordinated as a unidentate ligand and the oxime is functioning as a neutral ligand.
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U2 - 10.1016/S0277-5387(00)88001-8
DO - 10.1016/S0277-5387(00)88001-8
M3 - Article
AN - SCOPUS:0038987658
SN - 0277-5387
VL - 3
SP - 641
EP - 649
JO - Polyhedron
JF - Polyhedron
IS - 6
ER -