Synthesis and Characterization of Photo-Cross-Linkable Small-Molecule and High-Polymeric Phosphazenes Bearing Cinnamate Groups

Harry R. Allcock; Charles G. Cameron

doi:10.1021/ma00090a002

Synthesis and Characterization of Photo-Cross-Linkable Small-Molecule and High-Polymeric Phosphazenes Bearing Cinnamate Groups

Harry R. Allcock, Charles G. Cameron

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39 Scopus citations

Abstract

Cyclic trimeric and high-polymeric phosphazenes bearing cinnamate groups were synthesized and characterized. Cyclic trimers with the general formula N₃P₃R_yR_x′, where R = OC₆H₄OC(O)CH=CHPh, R′ = OCH₂CF₃ (y = 1, x = 5 and y = 6, x = 0), and R = (OCH₂CH₂)₂OC(O)CH=CHPh (y = 1, x = 5 and y = 6, x = 0) were synthesized. Also prepared were high-polymeric phosphazenes [NPR,R′y], where R = OC₆H₄OC(O)CH=CHPh, R′ = OCH₂CF₃ (y = x = 1 andy = 0, x = 2) and R = (OCH₂CH₂)₂OC(O)CH=CHPh (y = x = 1 and y = 0, x = 2). The photo-cross-linking of a representative polymer was studied by UV spectroscopy.

Original language	English (US)
Pages (from-to)	3125-3130
Number of pages	6
Journal	Macromolecules
Volume	27
Issue number	12
DOIs	https://doi.org/10.1021/ma00090a002
State	Published - Jun 1 1994

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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@article{0191a4d6b684465582440c6253343bf3,

title = "Synthesis and Characterization of Photo-Cross-Linkable Small-Molecule and High-Polymeric Phosphazenes Bearing Cinnamate Groups",

abstract = "Cyclic trimeric and high-polymeric phosphazenes bearing cinnamate groups were synthesized and characterized. Cyclic trimers with the general formula N3P3RyRx′, where R = OC6H4OC(O)CH=CHPh, R′ = OCH2CF3 (y = 1, x = 5 and y = 6, x = 0), and R = (OCH2CH2)2OC(O)CH=CHPh (y = 1, x = 5 and y = 6, x = 0) were synthesized. Also prepared were high-polymeric phosphazenes [NPR,R′y], where R = OC6H4OC(O)CH=CHPh, R′ = OCH2CF3 (y = x = 1 andy = 0, x = 2) and R = (OCH2CH2)2OC(O)CH=CHPh (y = x = 1 and y = 0, x = 2). The photo-cross-linking of a representative polymer was studied by UV spectroscopy.",

author = "Allcock, {Harry R.} and Cameron, {Charles G.}",

year = "1994",

month = jun,

day = "1",

doi = "10.1021/ma00090a002",

language = "English (US)",

volume = "27",

pages = "3125--3130",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "12",

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TY - JOUR

T1 - Synthesis and Characterization of Photo-Cross-Linkable Small-Molecule and High-Polymeric Phosphazenes Bearing Cinnamate Groups

AU - Allcock, Harry R.

AU - Cameron, Charles G.

PY - 1994/6/1

Y1 - 1994/6/1

N2 - Cyclic trimeric and high-polymeric phosphazenes bearing cinnamate groups were synthesized and characterized. Cyclic trimers with the general formula N3P3RyRx′, where R = OC6H4OC(O)CH=CHPh, R′ = OCH2CF3 (y = 1, x = 5 and y = 6, x = 0), and R = (OCH2CH2)2OC(O)CH=CHPh (y = 1, x = 5 and y = 6, x = 0) were synthesized. Also prepared were high-polymeric phosphazenes [NPR,R′y], where R = OC6H4OC(O)CH=CHPh, R′ = OCH2CF3 (y = x = 1 andy = 0, x = 2) and R = (OCH2CH2)2OC(O)CH=CHPh (y = x = 1 and y = 0, x = 2). The photo-cross-linking of a representative polymer was studied by UV spectroscopy.

AB - Cyclic trimeric and high-polymeric phosphazenes bearing cinnamate groups were synthesized and characterized. Cyclic trimers with the general formula N3P3RyRx′, where R = OC6H4OC(O)CH=CHPh, R′ = OCH2CF3 (y = 1, x = 5 and y = 6, x = 0), and R = (OCH2CH2)2OC(O)CH=CHPh (y = 1, x = 5 and y = 6, x = 0) were synthesized. Also prepared were high-polymeric phosphazenes [NPR,R′y], where R = OC6H4OC(O)CH=CHPh, R′ = OCH2CF3 (y = x = 1 andy = 0, x = 2) and R = (OCH2CH2)2OC(O)CH=CHPh (y = x = 1 and y = 0, x = 2). The photo-cross-linking of a representative polymer was studied by UV spectroscopy.

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U2 - 10.1021/ma00090a002

DO - 10.1021/ma00090a002

M3 - Article

AN - SCOPUS:0028766573

SN - 0024-9297

VL - 27

SP - 3125

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JO - Macromolecules

JF - Macromolecules

IS - 12

ER -

Synthesis and Characterization of Photo-Cross-Linkable Small-Molecule and High-Polymeric Phosphazenes Bearing Cinnamate Groups

Abstract

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