Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(II) and manganese(II)

Cynthia Brewer; Greg Brewer; Ray J. Butcher; Everett E. Carpenter; Luciann Cuenca; Ann Marie Schmiedekamp; Carol Viragh

doi:10.1039/b511566c

Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(II) and manganese(II)

Cynthia Brewer
, Greg Brewer
, Ray J. Butcher
, Everett E. Carpenter
, Luciann Cuenca
, Ann Marie Schmiedekamp
, Carol Viragh

Division of Engineering and Science (Abington)

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The iron(II) and manganese(II) complexes of the N₇ Schiff-base condensate of tris(3-aminopropyl)amine with 1-methyl-2-imidazolecarbaldehyde and the manganese(II) complex of the N₇ Schiff-base condensate of tris(3-aminopropyl)amine with 4-imidazolecarbaldehyde are high-spin mono capped octahedral seven-coordinate complexes with a short, ∼2.44 è, metal to apical nitrogen bond.

Original language	English (US)
Pages (from-to)	3617-3619
Number of pages	3
Journal	Dalton Transactions
Issue number	22
DOIs	https://doi.org/10.1039/b511566c
State	Published - Nov 21 2005

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/b511566c

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title = "Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(II) and manganese(II)",

abstract = "The iron(II) and manganese(II) complexes of the N7 Schiff-base condensate of tris(3-aminopropyl)amine with 1-methyl-2-imidazolecarbaldehyde and the manganese(II) complex of the N7 Schiff-base condensate of tris(3-aminopropyl)amine with 4-imidazolecarbaldehyde are high-spin mono capped octahedral seven-coordinate complexes with a short, ∼2.44 {\`e}, metal to apical nitrogen bond.",

author = "Cynthia Brewer and Greg Brewer and Butcher, \{Ray J.\} and Carpenter, \{Everett E.\} and Luciann Cuenca and Schmiedekamp, \{Ann Marie\} and Carol Viragh",

year = "2005",

month = nov,

day = "21",

doi = "10.1039/b511566c",

language = "English (US)",

pages = "3617--3619",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

number = "22",

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T1 - Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(II) and manganese(II)

AU - Brewer, Cynthia

AU - Brewer, Greg

AU - Butcher, Ray J.

AU - Carpenter, Everett E.

AU - Cuenca, Luciann

AU - Schmiedekamp, Ann Marie

AU - Viragh, Carol

PY - 2005/11/21

Y1 - 2005/11/21

N2 - The iron(II) and manganese(II) complexes of the N7 Schiff-base condensate of tris(3-aminopropyl)amine with 1-methyl-2-imidazolecarbaldehyde and the manganese(II) complex of the N7 Schiff-base condensate of tris(3-aminopropyl)amine with 4-imidazolecarbaldehyde are high-spin mono capped octahedral seven-coordinate complexes with a short, ∼2.44 è, metal to apical nitrogen bond.

AB - The iron(II) and manganese(II) complexes of the N7 Schiff-base condensate of tris(3-aminopropyl)amine with 1-methyl-2-imidazolecarbaldehyde and the manganese(II) complex of the N7 Schiff-base condensate of tris(3-aminopropyl)amine with 4-imidazolecarbaldehyde are high-spin mono capped octahedral seven-coordinate complexes with a short, ∼2.44 è, metal to apical nitrogen bond.

UR - https://www.scopus.com/pages/publications/27944437918

UR - https://www.scopus.com/pages/publications/27944437918#tab=citedBy

U2 - 10.1039/b511566c

DO - 10.1039/b511566c

M3 - Article

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AN - SCOPUS:27944437918

SN - 1477-9226

SP - 3617

EP - 3619

JO - Dalton Transactions

JF - Dalton Transactions

IS - 22

ER -

Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(II) and manganese(II)

Abstract

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