Synthesis and characterization of the mono- And di-meric complexes of Mn(III) with tridentate schiff base ligands: L L=N-(3-hydroxypropyl) salicydenimine, N-(3-hydroxypropyd-3-methoxyl-salicydenimine)

Cun Gen Zhang; Yong Jun Leng; Jian Ming Gu; Duan Jun Xu; Yuan Zhi Xu

Synthesis and characterization of the mono- And di-meric complexes of Mn(III) with tridentate schiff base ligands: L L=N-(3-hydroxypropyl) salicydenimine, N-(3-hydroxypropyd-3-methoxyl-salicydenimine)

Cun Gen Zhang, Yong Jun Leng, Jian Ming Gu, Duan Jun Xu, Yuan Zhi Xu

Mechanical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Six new complexes of Schiff base ligands, N-(3-hydroxypropyl) salicydenimine (H ₂salpa) and N-(3-hydroxypropyl)-3-methoxyl-salicydenimine (H ₂vanpa), coordinate to manganese (III) are synthesized, among which [Mn ₂(salpa) ₂(PhCOO) ₂] · 2CH ₂C1 ₂, [Mn ₂(vanpa) ₂(PhCOO) ₂] · 2CHCl ₃ and [Mn ₂ (vanpa) ₂ (ClCH ₂COO) ₂] are dimeric complexes, while [Mn(Hsalpa) ₂ (H ₂O) Cl], [Mn(vanpa) ₂(H ₂O)Br] and [Mn(Hsalpa) ₂(NCS)] are monomeric complexes. Their IR spectra have been assigned. The synthetic procedure is also discussed. [Mn ₂(vanpa) ₂(PhCOO)2] · 2CHCl ₃ is determined by X-ray crystal structural analysis. The Mn⋯Mn distance of 2. 848 Å is by far the shortest dimeric manganese (III) complex of this type.

Original language	English (US)
Pages (from-to)	x5-589
Journal	Chinese Journal of Inorganic Chemistry
Volume	15
Issue number	5
State	Published - 1999

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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@article{11ed8ad7062a45f29bbc3026df25e3c4,

title = "Synthesis and characterization of the mono- And di-meric complexes of Mn(III) with tridentate schiff base ligands: L L=N-(3-hydroxypropyl) salicydenimine, N-(3-hydroxypropyd-3-methoxyl-salicydenimine)",

abstract = "Six new complexes of Schiff base ligands, N-(3-hydroxypropyl) salicydenimine (H 2salpa) and N-(3-hydroxypropyl)-3-methoxyl-salicydenimine (H 2vanpa), coordinate to manganese (III) are synthesized, among which [Mn 2(salpa) 2(PhCOO) 2] · 2CH 2C1 2, [Mn 2(vanpa) 2(PhCOO) 2] · 2CHCl 3 and [Mn 2 (vanpa) 2 (ClCH 2COO) 2] are dimeric complexes, while [Mn(Hsalpa) 2 (H 2O) Cl], [Mn(vanpa) 2(H 2O)Br] and [Mn(Hsalpa) 2(NCS)] are monomeric complexes. Their IR spectra have been assigned. The synthetic procedure is also discussed. [Mn 2(vanpa) 2(PhCOO)2] · 2CHCl 3 is determined by X-ray crystal structural analysis. The Mn⋯Mn distance of 2. 848 {\AA} is by far the shortest dimeric manganese (III) complex of this type.",

author = "Zhang, {Cun Gen} and Leng, {Yong Jun} and Gu, {Jian Ming} and Xu, {Duan Jun} and Xu, {Yuan Zhi}",

year = "1999",

language = "English (US)",

volume = "15",

pages = "x5--589",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "5",

}

Synthesis and characterization of the mono- And di-meric complexes of Mn(III) with tridentate schiff base ligands: L L=N-(3-hydroxypropyl) salicydenimine, N-(3-hydroxypropyd-3-methoxyl-salicydenimine). / Zhang, Cun Gen; Leng, Yong Jun; Gu, Jian Ming et al.
In: Chinese Journal of Inorganic Chemistry, Vol. 15, No. 5, 1999, p. x5-589.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and characterization of the mono- And di-meric complexes of Mn(III) with tridentate schiff base ligands

T2 - L L=N-(3-hydroxypropyl) salicydenimine, N-(3-hydroxypropyd-3-methoxyl-salicydenimine)

AU - Zhang, Cun Gen

AU - Leng, Yong Jun

AU - Gu, Jian Ming

AU - Xu, Duan Jun

AU - Xu, Yuan Zhi

PY - 1999

Y1 - 1999

N2 - Six new complexes of Schiff base ligands, N-(3-hydroxypropyl) salicydenimine (H 2salpa) and N-(3-hydroxypropyl)-3-methoxyl-salicydenimine (H 2vanpa), coordinate to manganese (III) are synthesized, among which [Mn 2(salpa) 2(PhCOO) 2] · 2CH 2C1 2, [Mn 2(vanpa) 2(PhCOO) 2] · 2CHCl 3 and [Mn 2 (vanpa) 2 (ClCH 2COO) 2] are dimeric complexes, while [Mn(Hsalpa) 2 (H 2O) Cl], [Mn(vanpa) 2(H 2O)Br] and [Mn(Hsalpa) 2(NCS)] are monomeric complexes. Their IR spectra have been assigned. The synthetic procedure is also discussed. [Mn 2(vanpa) 2(PhCOO)2] · 2CHCl 3 is determined by X-ray crystal structural analysis. The Mn⋯Mn distance of 2. 848 Å is by far the shortest dimeric manganese (III) complex of this type.

AB - Six new complexes of Schiff base ligands, N-(3-hydroxypropyl) salicydenimine (H 2salpa) and N-(3-hydroxypropyl)-3-methoxyl-salicydenimine (H 2vanpa), coordinate to manganese (III) are synthesized, among which [Mn 2(salpa) 2(PhCOO) 2] · 2CH 2C1 2, [Mn 2(vanpa) 2(PhCOO) 2] · 2CHCl 3 and [Mn 2 (vanpa) 2 (ClCH 2COO) 2] are dimeric complexes, while [Mn(Hsalpa) 2 (H 2O) Cl], [Mn(vanpa) 2(H 2O)Br] and [Mn(Hsalpa) 2(NCS)] are monomeric complexes. Their IR spectra have been assigned. The synthetic procedure is also discussed. [Mn 2(vanpa) 2(PhCOO)2] · 2CHCl 3 is determined by X-ray crystal structural analysis. The Mn⋯Mn distance of 2. 848 Å is by far the shortest dimeric manganese (III) complex of this type.

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SN - 1001-4861

VL - 15

SP - x5-589

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

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Synthesis and characterization of the mono- And di-meric complexes of Mn(III) with tridentate schiff base ligands: L L=N-(3-hydroxypropyl) salicydenimine, N-(3-hydroxypropyd-3-methoxyl-salicydenimine)

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