Synthesis and crystal structure of a new europium nickel phosphide phase, EuNi5P3

John V. Badding; Angelica M. Stacy

doi:10.1016/0022-4596(87)90374-4

Synthesis and crystal structure of a new europium nickel phosphide phase, EuNi₅P₃

John V. Badding, Angelica M. Stacy

Chemistry

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16 Scopus citations

Abstract

A new europium nickel phosphide compound EuNi₅P₃ was synthesized in a tin flux. The structure was refined from single crystal X-ray data in the space group Cmcm to an R value of 2.06%. The lattice parameters are a = 3.5986(3), b = 11.7374(8), and c = 11.5230(10)Å and the compound is isotypic with LaCo₅P₃ and LaNi₅P₃. The room temperature magnetic moment of 8.1 Bohr magnetons indicates that the europium ions are in the +2 oxidation state.

Original language	English (US)
Pages (from-to)	354-358
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	67
Issue number	2
DOIs	https://doi.org/10.1016/0022-4596(87)90374-4
State	Published - Apr 1987

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-4596(87)90374-4

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title = "Synthesis and crystal structure of a new europium nickel phosphide phase, EuNi5P3",

abstract = "A new europium nickel phosphide compound EuNi5P3 was synthesized in a tin flux. The structure was refined from single crystal X-ray data in the space group Cmcm to an R value of 2.06%. The lattice parameters are a = 3.5986(3), b = 11.7374(8), and c = 11.5230(10){\AA} and the compound is isotypic with LaCo5P3 and LaNi5P3. The room temperature magnetic moment of 8.1 Bohr magnetons indicates that the europium ions are in the +2 oxidation state.",

author = "Badding, {John V.} and Stacy, {Angelica M.}",

note = "Funding Information: The crystal structurea nalysis was performedb y Dr. F. .I. Hollander, staff crystallographera t the U. C. Berkeley X-ray Crystallographic Facility (CHEX-RAY). Funds for the analysis were provided by a Presidential Young Investigator Award from the National Science Foundation (Grant number CHE835188)a nd matchingf unds from E. I. du Pont de Nemours and Company. The authors thank Dr. F. many valuable discussions.",

year = "1987",

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doi = "10.1016/0022-4596(87)90374-4",

language = "English (US)",

volume = "67",

pages = "354--358",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

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T1 - Synthesis and crystal structure of a new europium nickel phosphide phase, EuNi5P3

AU - Badding, John V.

AU - Stacy, Angelica M.

N1 - Funding Information: The crystal structurea nalysis was performedb y Dr. F. .I. Hollander, staff crystallographera t the U. C. Berkeley X-ray Crystallographic Facility (CHEX-RAY). Funds for the analysis were provided by a Presidential Young Investigator Award from the National Science Foundation (Grant number CHE835188)a nd matchingf unds from E. I. du Pont de Nemours and Company. The authors thank Dr. F. many valuable discussions.

PY - 1987/4

Y1 - 1987/4

N2 - A new europium nickel phosphide compound EuNi5P3 was synthesized in a tin flux. The structure was refined from single crystal X-ray data in the space group Cmcm to an R value of 2.06%. The lattice parameters are a = 3.5986(3), b = 11.7374(8), and c = 11.5230(10)Å and the compound is isotypic with LaCo5P3 and LaNi5P3. The room temperature magnetic moment of 8.1 Bohr magnetons indicates that the europium ions are in the +2 oxidation state.

AB - A new europium nickel phosphide compound EuNi5P3 was synthesized in a tin flux. The structure was refined from single crystal X-ray data in the space group Cmcm to an R value of 2.06%. The lattice parameters are a = 3.5986(3), b = 11.7374(8), and c = 11.5230(10)Å and the compound is isotypic with LaCo5P3 and LaNi5P3. The room temperature magnetic moment of 8.1 Bohr magnetons indicates that the europium ions are in the +2 oxidation state.

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DO - 10.1016/0022-4596(87)90374-4

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SN - 0022-4596

VL - 67

SP - 354

EP - 358

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

Synthesis and crystal structure of a new europium nickel phosphide phase, EuNi₅P₃

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