Synthesis and structure characterization of copper terephthalate metal-organic frameworks

Cantwell G. Carson; Kenneth Hardcastle; Justin Schwartz; Xiaotao Liu; Christina Hoffmann; Rosario A. Gerhardt; Rina Tannenbaum

doi:10.1002/ejic.200801224

Synthesis and structure characterization of copper terephthalate metal-organic frameworks

Cantwell G. Carson, Kenneth Hardcastle, Justin Schwartz, Xiaotao Liu, Christina Hoffmann, Rosario A. Gerhardt, Rina Tannenbaum

Research output: Contribution to journal › Article › peer-review

342 Scopus citations

Abstract

In this paper, we report on a high-throughput (gram quantities) solvothermal method for the synthesis of copper terephthalate metal-organic frameworks in dmf. While the structure of MOF-2 and some of the associated polymorphs are well known, we know of no equivalent structural studies for the isostructural copper terephthalate (Cu-tpa). The material we have made crystallizes in the C2/m space group. Cu-tpa also exhibits reversible solvent-exchange properties. These properties make this material useful for potential applications in gas storage and catalysis applications.

Original language	English (US)
Pages (from-to)	2338-2343
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Issue number	16
DOIs	https://doi.org/10.1002/ejic.200801224
State	Published - Jun 2009

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1002/ejic.200801224

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title = "Synthesis and structure characterization of copper terephthalate metal-organic frameworks",

abstract = "In this paper, we report on a high-throughput (gram quantities) solvothermal method for the synthesis of copper terephthalate metal-organic frameworks in dmf. While the structure of MOF-2 and some of the associated polymorphs are well known, we know of no equivalent structural studies for the isostructural copper terephthalate (Cu-tpa). The material we have made crystallizes in the C2/m space group. Cu-tpa also exhibits reversible solvent-exchange properties. These properties make this material useful for potential applications in gas storage and catalysis applications.",

author = "Carson, {Cantwell G.} and Kenneth Hardcastle and Justin Schwartz and Xiaotao Liu and Christina Hoffmann and Gerhardt, {Rosario A.} and Rina Tannenbaum",

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AU - Carson, Cantwell G.

AU - Hardcastle, Kenneth

AU - Schwartz, Justin

AU - Liu, Xiaotao

AU - Hoffmann, Christina

AU - Gerhardt, Rosario A.

AU - Tannenbaum, Rina

PY - 2009/6

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AB - In this paper, we report on a high-throughput (gram quantities) solvothermal method for the synthesis of copper terephthalate metal-organic frameworks in dmf. While the structure of MOF-2 and some of the associated polymorphs are well known, we know of no equivalent structural studies for the isostructural copper terephthalate (Cu-tpa). The material we have made crystallizes in the C2/m space group. Cu-tpa also exhibits reversible solvent-exchange properties. These properties make this material useful for potential applications in gas storage and catalysis applications.

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

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ER -

Synthesis and structure characterization of copper terephthalate metal-organic frameworks

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