Synthesis and thermal expansion behavior of Bai+xZr4P6-2xSi2xO24 and Sr1+xZr4P6-2xSi2xO24 systems

Chi Yuan Huang; Santosh Y. Limaye; H. A. McKinstry; D. K. Agrawal

doi:10.1557/JMR.1994.2005

Synthesis and thermal expansion behavior of Ba_i+xZr4P_6-2xSi_2xO₂₄ and Sr_1+xZr₄P_6-2xSi_2xO₂₄ systems

Chi Yuan Huang, Santosh Y. Limaye, H. A. McKinstry, D. K. Agrawal

Materials Research Institute (MRI)

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

NaZr2P3012 (NZP) is emerging as an important family of a large number of isostructural compounds in which several members have demonstrated very low thermal expansion characteristics. Ba_i+xZr4P_6-2xSi_2xO₂₄ and Sr_1+xZr₄P_6-2xSi_2xO₂₄ crystalline solutions are two such systems belonging to the NZP family. Here, we report the bulk thermal expansion and axial thermal expansion behavior of various compositions in these systems. The low expansion behavior of these materials is attributed to their unique crystal structure, which is framework open structure, and can accommodate numerous ionic substitutions at various lattice sites.

Original language	English (US)
Pages (from-to)	2005-2013
Number of pages	9
Journal	Journal of Materials Research
Volume	9
Issue number	8
DOIs	https://doi.org/10.1557/JMR.1994.2005
State	Published - Aug 1994

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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title = "Synthesis and thermal expansion behavior of Bai+xZr4P6-2xSi2xO24 and Sr1+xZr4P6-2xSi2xO24 systems",

abstract = "NaZr2P3012 (NZP) is emerging as an important family of a large number of isostructural compounds in which several members have demonstrated very low thermal expansion characteristics. Bai+xZr4P6-2xSi2xO24 and Sr1+xZr4P6-2xSi2xO24 crystalline solutions are two such systems belonging to the NZP family. Here, we report the bulk thermal expansion and axial thermal expansion behavior of various compositions in these systems. The low expansion behavior of these materials is attributed to their unique crystal structure, which is framework open structure, and can accommodate numerous ionic substitutions at various lattice sites.",

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AU - Huang, Chi Yuan

AU - Limaye, Santosh Y.

AU - McKinstry, H. A.

AU - Agrawal, D. K.

PY - 1994/8

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AB - NaZr2P3012 (NZP) is emerging as an important family of a large number of isostructural compounds in which several members have demonstrated very low thermal expansion characteristics. Bai+xZr4P6-2xSi2xO24 and Sr1+xZr4P6-2xSi2xO24 crystalline solutions are two such systems belonging to the NZP family. Here, we report the bulk thermal expansion and axial thermal expansion behavior of various compositions in these systems. The low expansion behavior of these materials is attributed to their unique crystal structure, which is framework open structure, and can accommodate numerous ionic substitutions at various lattice sites.

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Synthesis and thermal expansion behavior of Ba_i+xZr4P_6-2xSi_2xO₂₄ and Sr_1+xZr₄P_6-2xSi_2xO₂₄ systems

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