Synthesis and X-ray single crystal structure analysis of an inorganic nucleoside analog

Srećko I. Kirin; Kristi Ohr; Hemant P. Yennawar; Christopher M. Morgan; Lauren A. Levine; Mary Elizabeth Williams

doi:10.1016/j.inoche.2007.02.022

Synthesis and X-ray single crystal structure analysis of an inorganic nucleoside analog

Srećko I. Kirin, Kristi Ohr, Hemant P. Yennawar, Christopher M. Morgan, Lauren A. Levine, Mary Elizabeth Williams

Research output: Contribution to journal › Article › peer-review

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Abstract

The inorganic nucleoside analog [Boc-aeg{Cu(pda)py-Ac}-OMe] (3) is prepared and fully characterized. The X-ray single crystal analysis reveals that 3 assembles by apical Cu-O bonds into a coordination polymer, with short Cu-Cu distances of 5.32 and 5.78 Å. The solid state structure of 3 is in accordance with an isotactic structural model for charge neutral inorganic nucleic acids analogs. Aeg = (2-aminoethyl)glycine, py-Ac = 4-acetyl pyridine, pda = pyridine-2,6-dicarboxylic acid.

Original language	English (US)
Pages (from-to)	652-656
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2007.02.022
State	Published - Jun 2007

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2007.02.022

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@article{cd502f4d908a479290ac039a0238b7d7,

title = "Synthesis and X-ray single crystal structure analysis of an inorganic nucleoside analog",

abstract = "The inorganic nucleoside analog [Boc-aeg{Cu(pda)py-Ac}-OMe] (3) is prepared and fully characterized. The X-ray single crystal analysis reveals that 3 assembles by apical Cu-O bonds into a coordination polymer, with short Cu-Cu distances of 5.32 and 5.78 {\AA}. The solid state structure of 3 is in accordance with an isotactic structural model for charge neutral inorganic nucleic acids analogs. Aeg = (2-aminoethyl)glycine, py-Ac = 4-acetyl pyridine, pda = pyridine-2,6-dicarboxylic acid.",

author = "Kirin, {Sre{\'c}ko I.} and Kristi Ohr and Yennawar, {Hemant P.} and Morgan, {Christopher M.} and Levine, {Lauren A.} and Williams, {Mary Elizabeth}",

note = "Funding Information: The authors are grateful to the David and Lucile Packard Foundation, the Alfred P. Sloan Foundation and the NSF Chemistry Research Instrumentation and Facilities Grant CHE-0131112 for generous support of this work. The authors also thank Dr. Klaus Merz (Ruhr Universit{\"a}t Bochum) and Christopher J. Thode (Penn State University) for helpful discussions and James R. Miller (Penn State University) for assistance with acquisition of the mass spectra. ",

year = "2007",

month = jun,

doi = "10.1016/j.inoche.2007.02.022",

language = "English (US)",

volume = "10",

pages = "652--656",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "6",

}

TY - JOUR

T1 - Synthesis and X-ray single crystal structure analysis of an inorganic nucleoside analog

AU - Kirin, Srećko I.

AU - Ohr, Kristi

AU - Yennawar, Hemant P.

AU - Morgan, Christopher M.

AU - Levine, Lauren A.

AU - Williams, Mary Elizabeth

N1 - Funding Information: The authors are grateful to the David and Lucile Packard Foundation, the Alfred P. Sloan Foundation and the NSF Chemistry Research Instrumentation and Facilities Grant CHE-0131112 for generous support of this work. The authors also thank Dr. Klaus Merz (Ruhr Universität Bochum) and Christopher J. Thode (Penn State University) for helpful discussions and James R. Miller (Penn State University) for assistance with acquisition of the mass spectra.

PY - 2007/6

Y1 - 2007/6

N2 - The inorganic nucleoside analog [Boc-aeg{Cu(pda)py-Ac}-OMe] (3) is prepared and fully characterized. The X-ray single crystal analysis reveals that 3 assembles by apical Cu-O bonds into a coordination polymer, with short Cu-Cu distances of 5.32 and 5.78 Å. The solid state structure of 3 is in accordance with an isotactic structural model for charge neutral inorganic nucleic acids analogs. Aeg = (2-aminoethyl)glycine, py-Ac = 4-acetyl pyridine, pda = pyridine-2,6-dicarboxylic acid.

AB - The inorganic nucleoside analog [Boc-aeg{Cu(pda)py-Ac}-OMe] (3) is prepared and fully characterized. The X-ray single crystal analysis reveals that 3 assembles by apical Cu-O bonds into a coordination polymer, with short Cu-Cu distances of 5.32 and 5.78 Å. The solid state structure of 3 is in accordance with an isotactic structural model for charge neutral inorganic nucleic acids analogs. Aeg = (2-aminoethyl)glycine, py-Ac = 4-acetyl pyridine, pda = pyridine-2,6-dicarboxylic acid.

UR - http://www.scopus.com/inward/record.url?scp=34248189174&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34248189174&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2007.02.022

DO - 10.1016/j.inoche.2007.02.022

M3 - Article

AN - SCOPUS:34248189174

SN - 1387-7003

VL - 10

SP - 652

EP - 656

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

Synthesis and X-ray single crystal structure analysis of an inorganic nucleoside analog

Abstract

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